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Register a new userSilk reinforced with graphene or carbon nanotubes spun by spiders
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Here, we report the production of silk incorporating graphene and carbon nanotubes directly by spider spinning, after spraying spiders with the corresponding aqueous dispersions. We observe a significant increment of the mechanical properties with respect to the pristine silk, in terms of fracture strength, Youngs and toughness moduli. We measure a fracture strength up to 5.4 GPa, a Youngs modulus up to 47.8 GPa and a toughness modulus up to 2.1 GPa, or 1567 J/g, which, to the best of our knowledge, is the highest reported to date, even when compared to the current toughest knotted fibres. This approach could be extended to other animals and plants and could lead to a new class of bionic materials for ultimate applications.
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Many calculations require a simple classical model for the interactions between sp^2-bonded carbon atoms, as in graphene or carbon nanotubes. Here we present a new valence force model to describe these interactions. The calculated phonon spectrum of graphene and the nanotube breathing-mode energy agree well with experimental measurements and with ab initio calculations. The model does not assume an underlying lattice, so it can also be directly applied to distorted structures. The characteristics and limitations of the model are discussed.
Graphene nanoribbons with sub-nanometer widths are extremely interesting for nanoscale electronics and devices as they combine the unusual transport properties of graphene with the opening of a band gap due to quantum confinement in the lateral dimension. Strong research efforts are presently paid to grow such nanoribbons. Here we show the synthesis of 6- and 7-armchair graphene nanoribbons, with widths of 0.61 and 0.74 nm, and excitonic gaps of 1.83 and 2.18 eV, by high-temperature vacuum annealing of ferrocene molecules inside single-walled carbon nanotubes. The encapsulation of the so-obtained graphene nanoribbons is proved by atomic resolution electron microscopy, while their assignment is provided by a combination of an extensive wavelength-dependent Raman scattering characterization and quantum-chemical calculations. These findings enable a facile and scalable approach leading to the controlled growth and detailed analysis of well-defined sub-nanometer graphene nanoribbons.
In laboratories, ultrahigh magnetic fields are usually produced with very large currents through superconducting, resistive or hybrid magnets, which require extreme conditions, such as low temperature, huge cooling water or tens of megawatts of power. In this work we report that when single walled carbon nanotubes (SWNTs) are cut, there are magnetic moments at the shearing end of SWNTs. The average magnetic moment is found to be 41.5+-9.8uB per carbon atom in the end states with a width of 1 nm at temperature of 300.0K, suggesting ultrahigh magnetic fields can be produced. The dangling sigma and pi bonds of the carbon atoms at the shearing ends play important roles for this unexpectedly high magnetic moments because the oxidation temperature of cut SWNTs is found to be as low as 312 in dry air. Producing ultrahigh magnetic field with SWNTs has the advantage of working at higher working temperature and with low energy consumption, suggesting great potentials of applications.
We derive the generalized magneto-absorption spectra for curved graphene nanorib- bons and carbon nanotubes by using the Peierls tight-binding model. The main spectral characteristics and the optical selection rules result from the cooperative or competitive relationships between the geometric structure and a magnetic field. In curved ribbons, the dominant selection rule remains unchanged during the variation of the curvature. When the arc angle increases, the prominent peaks are split, with some even vanishing as the angle exceeds a critical value. In carbon nanotubes, the angular-momentum coupling induces extra selection rules, of which more are revealed due to the increase of either (both) of the factors: tube diameter and field strength. Particularly once the two factors exceed certain critical values, the optical spectra could reflect the quasi-Landau-level structures. The identifying features of the spec- tra provide insight into optical excitations for curved systems with either open or closed boundary condition.
It is important to understand the electronic interaction between single-walled carbon nanotubes (SWNTs) and graphene in order to use them efficiently in multifunctional hybrid devices. Here we deposited SWNT bundles on graphene-covered copper and SiO2 substrates by chemical vapor deposition and investigated the charge transfer between them by Raman spectroscopy. Our results revealed that, on both copper and SiO2 substrates, graphene donates electrons to the SWNTs, resulting in p-type doped graphene and n-type doped SWNTs.
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