We have developed Lumped Element Kinetic Inductance Detectors (LEKID) sensitive in the frequency band from 80 to 120~GHz. In this work, we take advantage of the so-called proximity effect to reduce the superconducting gap of Aluminium, otherwise strongly suppressing the LEKID response for frequencies smaller than 100~GHz. We have designed, produced and optically tested various fully multiplexed arrays based on multi-layers combinations of Aluminium (Al) and Titanium (Ti). Their sensitivities have been measured using a dedicated closed-circle 100 mK dilution cryostat and a sky simulator allowing to reproduce realistic observation conditions. The spectral response has been characterised with a Martin-Puplett interferometer up to THz frequencies, and with a resolution of 3~GHz. We demonstrate that Ti-Al LEKID can reach an optical sensitivity of about $1.4$ $10^{-17}$~$W/Hz^{0.5}$ (best pixel), or $2.2$ $10^{-17}$~$W/Hz^{0.5}$ when averaged over the whole array. The optical background was set to roughly 0.4~pW per pixel, typical for future space observatories in this particular band. The performance is close to a sensitivity of twice the CMB photon noise limit at 100~GHz which drove the design of the Planck HFI instrument. This figure remains the baseline for the next generation of millimetre-wave space satellites.
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