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Register a new userViral nematics in confined geometries
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Motivated by recent experiments on the rod-like virus bacteriophage fd, confined to circular and annular domains, we present a theoretical study of structural transitions in these geometries. Using the continuum theory of nematic liquid crystals, we examine the competition between bulk elasticity and surface anchoring, mediated by the formation of topological defects. We show analytically that bulk defects are unstable with respect to defects sitting at the boundary. Moreover, in case of an annulus, whose topology does not require the presence of topological defects, under weak anchoring conditions we find that nematic textures with boundary defects are stable compared to the defect free configurations. Thus our simple approach, with no fitting parameters, suggests a possible symmetry breaking mechanism responsible for the formation of one-, two- and three-fold textures under annular confinement.
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Transport of ions in molecular-scale confined spaces is central to all aspects of life and technology: into a crack, it may break steel within days; through a membrane separator, it determines the efficiency of electrochemical energy conversion devices; or through lipid membranes, it steers neural communication. Yet, the direct observation of ion mobility and structuring in sub-nanometer confinement is experimentally challenging and, so far, solely accessible to molecular simulations. Here, we show quantitative, 3D molecularly-resolved ion transportation of aqueous ionic liquid and s-block metal ion solutions, confined to electrochemically-modulated, molecular-sized slits. Our analysis of atomically resolved solid/liquid interface unveils generic rules of how enthalpic ion-ion and ion-surface interactions and entropic confinement effects determine the charge regulation mechanism. Altering our general understanding, the confined charge regulation may proceed via fast, kinetically favoured, metastable pathways, followed by slow diffusive thermodynamic ion reorganization, which has important implications for all charge-regulated systems.
The Vicsek model (Vicsek et al. 1995) is a very popular minimalist model to study active matter with a number of applications to biological systems at different length scales. With its off-lattice implementation and the periodic boundary conditions, it aims at the analysis of bulk behaviour of a limited number of particles. To expand the applicability of the model to further biological systems, we introduce an on-lattice implementation and analyse its behaviour for three different geometries with reflective boundary conditions. For sufficiently fine lattices, the model behaviour does not differ between off-lattice and on-lattice implementation. The reflective boundary conditions introduce an alignment of the particles with the boundary for low levels of noise. Numerical sensitivity analysis of the swarming behaviour results in a detailed characterisation of the Vicsek model for confined geometries with reflective boundary conditions. In a channel geometry, the boundary alignment causes swarms to move along the channel. In a box, the edges act as swarm traps and the trapping shows a discontinuous noise dependence. In a disk geometry, an ordered rotational state arises. This state is well described by a novel order parameter. These results provide the basis for applications of the Vicsek model to biological questions involving large particle numbers in confined environments.
We develop an energetic model that captures the twisting behavior of spindle-shaped polymer microparticles with nematic ordering, which display remarkably different twisting behavior to ordinary nematics confined to spindles. We have previously developed a geometric model of the twisting, based on experimental observations, in which we showed that the twist pattern follows loxodrome spirals [Ansell et. al., Phys. Rev. Lett., 123, 157801 (2019)]. In this study, we first consider a spindle-shaped surface and show that the loxodrome twisting behavior of our system can be captured by the Frank free energy of the nematic with an additional term constraining the length of the integral curves of the system. We then extend the ideas of this model to the bulk and explore the parameter space for which the twisted loxodrome solution is energetically favorable.
We consider a two-dimensional gas of colliding charged particles confined to finite size containers of various geometries and subjected to a uniform orthogonal magnetic field. The gas spectral densities are characterized by a broad peak at the cyclotron frequency. Unlike for infinitely extended gases, where the amplitude of the cyclotron peak grows linearly with temperature, here confinement causes such a peak to go through a maximum for an optimal temperature. In view of the fluctuation-dissipation theorem, the reported resonance effect has a direct counterpart in the electric susceptibility of the confined magnetized gas.
We examine the scaling with activity of the emergent length scales that control the nonequilibrium dynamics of an active nematic liquid crystal, using two popular hydrodynamic models that have been employed in previous studies. In both models we find that the chaotic spatio-temporal dynamics in the regime of fully developed active turbulence is controlled by a single active scale determined by the balance of active and elastic stresses, regardless of whether the active stress is extensile or contractile in nature. The observed scaling of the kinetic energy and enstropy with activity is consistent with our single-length scale argument and simple dimensional analysis. Our results provide a unified understanding of apparent discrepancies in the previous literature and demonstrate that the essential physics is robust to the choice of model.
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