Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userThe infrared dielectric function of solid para-hydrogen
123
0
0.0
(
0
)
Authors
Cassie Kettwich
Ask ChatGPT about the research
No Arabic abstract
We report laboratory measurements of the absorption coefficient of solid para-H2, within the wavelength range from 1 to 16.7 micron, at high spectral resolution. In addition to the narrow rovibrational lines of H2 which are familiar from gas phase spectroscopy, the data manifest double transitions and broad phonon branches that are characteristic specifically of hydrogen in the solid phase. These transitions are of interest because they provide a spectral signature which is independent of the impurity content of the matrix. We have used our data, in combination with a model of the ultraviolet absorptions of the H2 molecule, to construct the dielectric function of solid para-H2 over a broad range of frequencies. Our results will be useful in determining the electromagnetic response of small particles of solid hydrogen. The dielectric function makes it clear that pure H2 dust would contribute to IR extinction predominantly by scattering starlight, rather than absorbing it, and the characteristic IR absorption spectrum of the hydrogen matrix itself will be difficult to observe.
rate research
Read More
We consider the possibility that solid molecular hydrogen is present in interstellar space. If so cosmic-rays and energetic photons cause ionisation in the solid leading to the formation of H6+. This ion is not produced by gas-phase reactions and its radiative transitions therefore provide a signature of solid H2 in the astrophysical context. The vibrational transitions of H6+ are yet to be observed in the laboratory, but we have characterised them in a quantum-theoretical treatment of the molecule; our calculations include anharmonic corrections, which are large. Here we report on those calculations and compare our results with astronomical data. In addition to the H6+ isotopomer, we focus on the deuterated species (HD)3+ which is expected to dominate at low ionisation rates as a result of isotopic condensation reactions. We can reliably predict the frequencies of the fundamental bands for five modes of vibration. For (HD)3+ all of these are found to lie close to some of the strongest of the pervasive mid-infrared astronomical emission bands, making it difficult to exclude hydrogen precipitates on observational grounds. By the same token these results suggest that (HD)3+ could be the carrier of the observed bands. We consider this possibility within the broader picture of ISM photo-processes and we conclude that solid hydrogen may indeed be abundant in astrophysical environments.
Adsorption of para-Hydrogen on the outer surface of a single fullerene is studied theoretically, by means of ground state Quantum Monte Carlo simulations. We compute energetics and radial density profiles of para-Hydrogen for various coverages on a variety of small fullerenes. The equilibrium adsorbed monolayer is commensurate with the surface of the fullerene; as the chemical potential is increased, a discontinuous change is generally observed, to an incommensurate, compressible layer. Quantum exchanges of Hydrogen molecules are absent in these systems.
We apply a spectral stacking technique to Westerbork Synthesis Radio Telescope observations to measure the neutral atomic hydrogen content (HI) of nearby galaxies in and around galaxy groups at $z < 0.11$. Our sample includes 577 optically-selected galaxies (120 isolated galaxies and 457 satellites) covering stellar masses between 10$^{10}$ and 10$^{11.5}$ M$_{odot}$, cross-matched with Yangs group catalogue, with angular and redshift positions from the Sloan Digital Sky Survey. We find that the satellites in the centres of groups have lower HI masses at fixed stellar mass and morphology (characterised by the inverse concentration index) relative to those at larger radii. These trends persist for satellites in both high-mass ($M_{rm halo} > 10^{13.5}h^{-1}$M$_{odot}$) and low-mass ($M_{rm halo} leqslant 10^{13.5}h^{-1}$M$_{odot}$) groups, but disappear if we only consider group members in low local density ($Sigma <$ 5 gal/Mpc$^{-2}$) environments. Similar trends are found for the specific star formation rate. Interestingly, we find that the radial trends of decreasing HI mass with decreasing group-centric radius extend beyond the group virial radius, as isolated galaxies close to larger groups lack HI compared with those located more than $sim$3.0 $R_{180}$ away from the center of their nearest group. We also measure these trends in the late-type subsample and obtain similar results. Our results suggest that the HI reservoir of galaxies can be affected before galaxies become group satellites, indicating the existence of pre-processing in the infalling isolated galaxies.
Mid-infrared molecular hydrogen (H$_2$) emission is a powerful cooling agent in galaxy mergers and in radio galaxies; it is a potential key tracer of gas evolution and energy dissipation associated with mergers, star formation, and accretion onto supermassive black holes. We detect mid-IR H$_2$ line emission in at least one rotational transition in 91% of the 214 Luminous Infrared Galaxies (LIRGs) observed with Spitzer as part of the Great Observatories All-sky LIRG Survey (GOALS). We use H$_2$ excitation diagrams to estimate the range of masses and temperatures of warm molecular gas in these galaxies. We find that LIRGs in which the IR emission originates mostly from the Active Galactic Nuclei (AGN) have about 100K higher H$_2$ mass-averaged excitation temperatures than LIRGs in which the IR emission originates mostly from star formation. Between 10 and 15% of LIRGs have H$_2$ emission lines that are sufficiently broad to be resolved or partially resolved by the high resolution modules of Spitzers Infrared Spectrograph (IRS). Those sources tend to be mergers and contain AGN. This suggests that a significant fraction of the H$_2$ line emission is powered by AGN activity through X-rays, cosmic rays, and turbulence. We find a statistically significant correlation between the kinetic energy in the H$_2$ gas and the H$_2$ to IR luminosity ratio. The sources with the largest warm gas kinetic energies are mergers. We speculate that mergers increase the production of bulk in-flows leading to observable broad H$_2$ profiles and possibly denser environments.
Molecular species, most frequently H_2, are present in a small, but growing, number of gamma-ray burst (GRB) afterglow spectra at redshifts z~2-3, detected through their rest-frame UV absorption lines. In rare cases, lines of vibrationally excited states of H_2 can be detected in the same spectra. The connection between afterglow line-of-sight absorption properties of molecular (and atomic) gas, and the observed behaviour in emission of similar sources at low redshift, is an important test of the suitability of GRB afterglows as general probes of conditions in star formation regions at high redshift. Recently, emission lines of carbon monoxide have been detected in a small sample of GRB host galaxies, at sub-mm wavelengths, but no searches for H_2 in emission have been reported yet. In this paper we perform an exploratory search for rest-frame K band rotation-vibrational transitions of H_2 in emission, observable only in the lowest redshift GRB hosts (z<0.22). Searching the data of four host galaxies, we detect a single significant rotation-vibrational H_2 line candidate, in the host of GRB 031203. Re-analysis of Spitzer mid-infrared spectra of the same GRB host gives a single low significance rotational line candidate. The (limits on) line flux ratios are consistent with those of blue compact dwarf galaxies in the literature. New instrumentation, in particular on the JWST and the ELT, can facilitate a major increase in our understanding of the H_2 properties of nearby GRB hosts, and the relation to H_2 absorption in GRBs at higher redshift.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
