In this Letter we model the chemistry of DCO$^{+}$ in protoplanetary disks. We find that the overall distribution of the DCO$^{+}$ abundance is qualitatively similar to that of CO but is dominated by thin layer located at the inner disk surface. To understand its distribution, we investigate the different key gas-phase deuteration pathways that can lead to the formation of DCO$^{+}$. Our analysis shows that the recent update in the exothermicity of the reaction involving CH$_2$D$^{+}$ as a parent molecule of DCO$^{+}$ favors deuterium fractionation in warmer conditions. As a result the formation of DCO$^{+}$ is enhanced in the inner warm surface layers of the disk where X-ray ionization occurs. Our analysis points out that DCO$^{+}$ is not a reliable tracer of the CO snow line as previously suggested. We thus predict that DCO$^{+}$ is a tracer of active deuterium and in particular X-ray ionization of the inner disk.
Due to instrumental limitations and a lack of disk detections, the structure between the envelope and the rotationally supported disk has been poorly studied. This is now possible with ALMA through observations of CO isotopologs and tracers of freezeout. Class 0 sources are ideal for such studies given their almost intact envelope and young disk. The structure of the disk-envelope interface of the prototypical Class 0 source, VLA1623A which has a confirmed Keplerian disk, is constrained from ALMA observations of DCO+ 3-2 and C18O 2-1. The physical structure of VLA1623 is obtained from the large-scale SED and continuum radiative transfer. An analytic model using a simple network coupled with radial density and temperature profiles is used as input for a 2D line radiative transfer calculation for comparison with the ALMA Cycle 0 12m array and Cycle 2 ACA observations of VLA1623. DCO+ emission shows a clumpy structure bordering VLA1623As Keplerian disk, suggesting a cold ring-like structure at the disk-envelope interface. The radial position of the observed DCO+ peak is reproduced in our model only if the regions temperature is between 11-16K, lower than expected from models constrained by continuum and SED. Altering the density has little effect on the DCO+ position, but increased density is needed to reproduce the disk traced in C18O. The DCO+ emission around VLA1623A is the product of shadowing of the envelope by the disk. Disk-shadowing causes a drop in the gas temperature outside of the disk on >200AU scales, encouraging deuterated molecule production. This indicates that the physical structure of the disk-envelope interface differs from the rest of the envelope, highlighting the drastic impact that the disk has on the envelope and temperature structure. The results presented here show that DCO+ is an excellent cold temperature tracer.
We aim to reproduce the DCO$^+$ emission in the disk around HD163296 using a simple 2D chemical model for the formation of DCO$^+$ through the cold deuteration channel and a parametric treatment of the warm deuteration channel. We use data from ALMA in band 6 to obtain a resolved spectral imaging data cube of the DCO$^+$ $J$=3--2 line in HD163296 with a synthesized beam of 0.53$times$ 0.42. We adopt a physical structure of the disk from the literature that reproduces the spectral energy distribution. We then apply a simplified chemical network for the formation of DCO$^+$ that uses the physical structure of the disk as parameters along with a CO abundance profile, a constant HD abundance and a constant ionization rate. Finally, from the resulting DCO$^+$ abundances, we calculate the non-LTE emission using the 3D radiative transfer code LIME. The observed DCO$^+$ emission is reproduced by a model with cold deuteration producing abundances up to $1.6times 10^{-11}$. Warm deuteration, at a constant abundance of $3.2times 10^{-12}$, becomes fully effective below 32 K and tapers off at higher temperatures, reproducing the lack of DCO$^+$ inside 90 AU. Throughout the DCO$^+$ emitting zone a CO abundance of $2times 10^{-7}$ is found, with $sim$99% of it frozen out below 19 K. At radii where both cold and warm deuteration are active, warm deuteration contributes up to 20% of DCO$^+$, consistent with detailed chemical models. The decrease of DCO$^+$ at large radii is attributed to a temperature inversion at 250 AU, which raises temperatures above values where cold deuteration operates. Increased photodesorption may also limit the radial extent of DCO$^+$. The corresponding return of the DCO$^+$ layer to the midplane, together with a radially increasing ionization fraction, reproduces the local DCO$^+$ emission maximum at $sim$260 AU.
We report the first detection of DCO+ in a circumstellar disk. The DCO+ J=5-4 line at 360.169 GHz is observed with the 15m James Clerk Maxwell Telescope in the disk around the pre-main sequence star TW Hya. Together with measurements of the HCO+ and H13CO+ J=4-3 lines, this allows an accurate determination of the DCO+/HCO+ ratio in this disk. The inferred value of 0.035+-0.015 is close to that found in cold pre-stellar cores and is somewhat higher than that measured in the envelope around the low-mass protostar IRAS 16293 -2422. It is also close to the DCN/HCN ratio obtained for pristine cometary material in the jet of comet Hale-Bopp. The observed DCO+/HCO+ ratio for TW Hya is consistent with theoretical models of disks which consider gas-phase fractionation processes within a realistic 2-D temperature distribution and which include the effects of freeze-out onto grains.
The high spatial and line sensitivity of ALMA opens the possibility of resolving emission from molecules in circumstellar disks. With an understanding of physical conditions under which molecules have high abundance, they can be used as direct tracers of distinct physical regions. In particular, DCO+ is expected to have an enhanced abundance within a few Kelvin of the CO freezeout temperature of 19 K, making it a useful probe of the cold disk midplane. We compare ALMA line observations of HD 163296 to a grid of models. We vary the upper- and lower-limit temperatures of the region in which DCO+ is present as well as the abundance of DCO+ in order to fit channel maps of the DCO+ J=5-4 line. To determine the abundance enhancement compared to the general interstellar medium, we carry out similar fitting to HCO+ J=4-3 and H13CO+ J=4-3 observations. ALMA images show centrally peaked extended emission from HCO+ and H13CO+. DCO+ emission lies in a resolved ring from ~110 to 160 AU. The outer radius approximately corresponds to the size of the CO snowline as measured by previous lower resolution observations of CO lines in this disk. The ALMA DCO+ data now resolve and image the CO snowline directly. In the best fitting models, HCO+ exists in a region extending from the 19 K isotherm to the photodissociation layer with an abundance of 3x10^-10 relative to H2. DCO+ exists within the 19-21 K region of the disk with an abundance ratio [DCO+] / [HCO+] = 0.3. This represents a factor of 10^4 enhancement of the DCO+ abundance within this narrow region of the HD 163296 disk. Such a high enhancement has only previously been seen in prestellar cores. The inferred abundances provide a lower limit to the ionization fraction in the midplane of the cold outer disk (approximately greater than 4x10^-10), and suggest the utility of DCO+ as a tracer of its parent molecule H2D+. Abridged
Stars form with gaseous and dusty circumstellar envelopes, which rapidly settle into disks that eventually give rise to planetary systems. Understanding the process by which these disks evolve is paramount in developing an accurate theory of planet formation that can account for the variety of planetary systems discovered so far. The formation of Earth-like planets through collisional accumulation of rocky objects within a disk has mainly been explored in theoretical and computational work in which post-collision ejecta evolution is typically ignored, although recent work has considered the fate of such material. Here we report observations of a young, Sun-like star (TYC 8241 2652 1) where infrared flux from post-collisional ejecta has decreased drastically, by a factor of about 30, over a period of less than two years. The star seems to have gone from hosting substantial quantities of dusty ejecta, in a region analogous to where the rocky planets orbit in the Solar System, to retaining at most a meagre amount of cooler dust. Such a phase of rapid ejecta evolution has not been previously predicted or observed, and no currently available physical model satisfactorily explains the observations.