This white paper addresses selected new (to X-ray astronomy) physics and data analysis issues that will impact ASTRO-H SWG observations as a result of its high-spectral-resolution X-ray microcalorimeter, the focussing hard X-ray optics and corresponding detectors, and the low background soft gamma-ray detector. We concentrate on issues of atomic and nuclear physics, including basic bound-bound and bound-free transitions as well as scattering and radiative transfer. The major topic categories include the physics of charge exchange, solar system X-ray sources, advanced spectral model, radiative transfer, and hard X-ray emission lines and sources.
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