We provide experimental evidence of quantum features in bi-partite states classified as entirely classical according to a conventional criterion based on the Glauber P-function but possessing non-zero Gaussian quantum discord. Their quantum nature is experimentally revealed by acting locally on one part of the discordant state. Adding an environmental system purifying the state, we unveil the flow of quantum correlations within a global pure system using the Koashi-Winter inequality. We experimentally verify and investigate the counterintuitive effect of discord increase under the action of local loss and link it to the entanglement with the environment. For a discordant state generated by splitting a state in which the initial squeezing is destroyed by random displacements, we demonstrate the recovery of entanglement highlighting the role of system-environment correlations.