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Register a new userDirectional depletion interactions in shaped particles
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Entropic forces in colloidal suspensions and in polymer-colloid systems are of long-standing and continuing interest. Experiments show how entropic forces can be used to control the self-assembly of colloidal particles. Significant advances in colloidal synthesis made in the past two decades have enabled the preparation of high quality nano-particles with well-controlled sizes, shapes, and compositions, indicating that such particles can be utilized as artificial atoms to build new materials. To elucidate the effects of the shape of particles upon the magnitude of entropic interaction, we analyse the entropic interactions of two cut-spheres. We show that the solvent induces a strong directional depletion attraction among flat faces of the cut-spheres. Such an effect highlights the possibility of using the shape of particles to control directionality and strength of interaction.
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Architectural structures such as masonry walls or columns exhibit a slender verticality, in contrast to the squat, sloped forms obtained with typical unconfined granular materials. Here we demonstrate the ability to create freestanding, weight-bearing, similarly slender and vertical structures by the simple pouring of suitably shaped dry particles into a mold that is subsequently removed. Combining experiments and simulations we explore a family of particle types that can entangle through their non-convex, hooked shape. We show that Z-shaped particles produce granular aggregates which can either be fluid and pourable, or solid and rigid enough to maintain vertical interfaces and build freestanding columns of large aspect ratio (>10) that support compressive loads without external confinement. We investigate the stability of such columns with uniaxial compression, bending, and vibration tests and compare with other particle types including U-shaped particles and rods. We find a pronounced anisotropy in the internal stress propagation together with strong strain-stiffening, which stabilizes rather than destabilizes the structures under load.
We study steady-state properties of a suspension of active, nonchiral and chiral, Brownian particles with polar alignment and steric interactions confined within a ring-shaped (annulus) confinement in two dimensions. Exploring possible interplays between polar interparticle alignment, geometric confinement and the surface curvature, being incorporated here on minimal levels, we report a surface-population reversal effect, whereby active particles migrate from the outer concave boundary of the annulus to accumulate on its inner convex boundary. This contrasts the conventional picture, implying stronger accumulation of active particles on concave boundaries relative to the convex ones. The population reversal is caused by both particle alignment and surface curvature, disappearing when either of these factors is absent. We explore the ensuing consequences for the chirality-induced current and swim pressure of active particles and analyze possible roles of system parameters, such as the mean number density of particles and particle self-propulsion, chirality and alignment strengths.
We study indented spherical colloids, interacting via depletion forces. These systems exhibit liquid-vapor phase transitions whose properties are determined by a combination of strong lock-and-key bonds and weaker non-specific interactions. As the propensity for lock-and-key binding increases, the critical point moves to significantly lower density, and the coexisting phases change their structure. In particular, the liquid phase is porous, exhibiting large percolating voids. The properties of this system depend strongly on the topological structure of an underlying bond network: we comment on the implications of this fact for the assembly of equilibrium states with controlled porous structures.
We analyze the dynamics of an active tracer particle embedded in a thermal lattice gas. All particles are subject to exclusion up to third nearest neighbors on the square lattice, which leads to slow dynamics at high densities. For the case with no rotational diffusion of the tracer, we derive an analytical expression for the resulting drift velocity v of the tracer in terms of non-equilibrium density correlations involving the tracer particle and its neighbors, which we verify using numerical simulations. We show that the properties of the passive system alone do not adequately describe even this simple system of a single non-rotating active tracer. For large activity and low density, we develop an approximation for v. For the case where the tracer undergoes rotational diffusion independent of its neighbors, we relate its diffusion coefficient to the thermal diffusion coefficient and v. Finally we study dynamics where the rotation of the tracer is limited by the presence of neighboring particles. We find that the effect of this rotational locking may be quantitatively described in terms of a reduction of the rotation rate.
We study a gaseous Bose-Einstein condensate with laser-induced dipole-dipole interactions using the Hartree-Fock-Bogoliubov theory within the Popov approximation. The dipolar interactions introduce long-range atom-atom correlations, which manifest themselves as increased depletion at momenta similar to that of the laser wavelength, as well as a roton dip in the excitation spectrum. Surprisingly, the roton dip and the corresponding peak in the depletion are enhanced by raising the temperature above absolute zero.
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