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Register a new userForbidden oxygen lines at various nucleocentric distances in comets
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To study the formation of the [OI] lines - i.e., 5577 A (the green line), 6300 A and 6364 A (the two red lines) - in the coma of comets and to determine the parent species of the oxygen atoms using the green to red-doublet emission intensity ratio (G/R ratio) and the lines velocity widths. We acquired at the ESO VLT high-resolution spectroscopic observations of comets C/2002 T7 (LINEAR), 73P-C/Schwassmann-Wachmann 3, 8P/Tuttle, and, 103P/Hartley 2 when they were close to the Earth (< 0.6 au). Using the observed spectra, we determined the intensities and the widths of the three [OI] lines. We have spatially extracted the spectra in order to achieve the best possible resolution of about 1-2, i.e., nucleocentric projected distances of 100 to 400 km depending on the geocentric distance of the comet. We have decontaminated the [OI] green line from C2 lines blends. It is found that the observed G/R ratio on all four comets varies as a function of nucleocentric projected distance. This is mainly due to the collisional quenching of O(1S) and O(1D) by water molecules in the inner coma. The observed green emission line width is about 2.5 km/s and decreases as the distance from the nucleus increases which can be explained by the varying contribution of CO2 to the O(1S) production in the innermost coma. The photodissociation of CO2 molecules seems to produce O(1S) closer to the nucleus while the water molecule forms all the O(1S) and O(1D) atoms beyond 1000 km. Thus we conclude that the main parent species producing O(1S) and O(1D) in the inner coma is not always the same. The observations have been interpreted in the framework of the coupled-chemistry-emission model of Bhardwaj & Raghuram (2012) and the upper limits of CO2 relative abundances are derived from the observed G/R ratios. Measuring the [OI] lines could indeed provide a new way to determine the CO2 relative abundance in comets.
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We present a study of the three forbidden oxygen lines [OI] located in the optical region (i.e., 5577.339 r{A} (the green line), 6300.304 r{A} and 6363.776 r{A} (the two red lines)) in order to better understand the production of these atoms in cometary atmospheres. The analysis is based on 48 high-resolution and high signal-to-noise spectra collected with UVES at the ESO VLT between 2003 and 2011 referring to 12 comets of different origins observed at various heliocentric distances. The flux ratio of the green line to the sum of the two red lines is evaluated to determine the parent species of the oxygen atoms by comparison with theoretical models. This analysis confirms that, at about 1 AU, H2O is the main parent molecule producing oxygen atoms. At heliocentric distances > 2.5 AU, this ratio is changing rapidly, an indication that other molecules are starting to contribute. CO and CO2, the most abundant species after H2O in the coma, are good candidates and the ratio is used to estimate their abundances. We found that the CO2 abundance relative to H2O in comet C/2001 Q4 (NEAT) observed at 4 AU can be as high as ~70 %. The intrinsic widths of the oxygen lines were also measured. The green line is on average about 1 km/s broader than the red lines while the theory predicts the red lines to be broader. This might be due to the nature of the excitation source and/or a contribution of CO2 as parent molecule of the 5577.339 r{A} line. At 4 AU, we found that the width of the green and red lines in comet C/2001 Q4 are the same which could be explained if CO2 becomes the main contributor for the three [OI] lines at high heliocentric distances.
The N$_2$ and CO-rich and water-depleted comet C/2016 R2 (Pan-STARRS) (hereafter `C/2016 R2) is a unique comet for detailed spectroscopic analysis. We aim to explore the associated photochemistry of parent species, which produces different metastable states and forbidden emissions, in this cometary coma of peculiar composition. We re-analyzed the high-resolution spectra of comet C/2016 R2, which were obtained in February 2018, using the UVES spectrograph of the European Southern Observatory (ESO) Very Large Telescope (VLT). Various forbidden atomic emission lines of [CI], [NI], and [OI] were observed in the optical spectrum of this comet when it was at 2.8 au from the Sun. The observed forbidden emission intensity ratios are studied in the framework of a couple-chemistry emission model. The model calculations show that CO$_2$ is the major source of both atomic oxygen green and red-doublet emissions in the coma of C/2016 R2 (while for most comets it is generally H$_2$O), whereas, CO and N$_2$ govern the atomic carbon and nitrogen emissions, respectively. Our modelled oxygen green to red-doublet and carbon to nitrogen emission ratios are higher by a factor {of 3}, when compared to the observations. These discrepancies can be due to uncertainties associated with photon cross sections or unknown production/loss sources. Our modelled oxygen green to red-doublet emission ratio is close to the observations, when we consider an O$_2$ abundance with a production rate of 30% relative to the CO production rate. The collisional quenching is not a significant loss process for N($^2$D) though its radiative lifetime is significant ($sim$10 hrs). Hence, the observed [NI] doublet-emission ratio ([NI] 5198/5200) of 1.22, which is smaller than the terrestrial measurement by a factor {1.4}, is mainly due to the characteristic radiative decay of N($^2$D).
Recently, Nadir and Occultation for Mars Discovery (NOMAD) ultraviolet and visible spectrometer instrument on board the European Space Agencys ExoMars Trace Gas Orbiter (TGO) simultaneously measured the limb emission intensities for both [OI] 2972 and 5577 {AA} (green) emissions in the dayside of Martian upper atmosphere. We aim to explore the photochemistry of all these forbidden atomic oxygen emissions ([OI] 2972, 5577, 6300, 6464 {AA}) in the Martian daylight upper atmosphere and suitable conditions for the simultaneous detection of these emissions lines in the dayside visible spectra. A photochemical model is developed to study the production and loss processes of O(1S) and O(1D) by incorporating various chemical reactions of different O-bearing species in the upper atmosphere of Mars. By reducing Fox (2004) modelled neutral density profiles by a factor of 2, the calculated limb intensity profiles for [OI] 5577 and 2972 {AA} emissions are found to be consistent with the NOMAD-TGO observations. In this case, at altitudes below 120 km, our modelled limb intensity for [OI] 6300 {AA} emission is smaller by a factor 2 to 5 compared to that of NOMAD-TGO observation for [OI] 2972 {AA} emission, and above this distance it is comparable with the upper limit of the observation. We studied various parameters which can influence the limb intensities of these atomic oxygen forbidden emission lines. Our calculated limb intensity for [OI] 6300 {AA} emission, when the Mars is at near perihelion and for solar maximum condition, suggests that all these forbidden emissions should be observable in the NOMAD-TGO visible spectra taken on the dayside of Martian upper atmosphere. More simultaneous observations of forbidden atomic oxygen emission lines will help to understand the photochemical processes of oxygen-bearing species in the dayside Martian upper atmosphere.
In the Sun, the two forbidden [OI] lines at 630 and 636 nm were previously found to provide discrepant oxygen abundances. aims: We investigate whether this discrepancy is peculiar to the Sun or whether it is also observed in other stars. method: We make use of high-resolution, high signal-to-noise ratio spectra of four dwarf to turn-off stars, five giant stars, and one sub-giant star observed with THEMIS, HARPS, and UVES to investigate the coherence of the two lines. results: The two lines provide oxygen abundances that are consistent, within observational errors, in all the giant stars examined by us. On the other hand, for the two dwarf stars for which a measurement was possible, for Procyon, and for the sub-giant star Capella, the 636 nm line provides systematically higher oxygen abundances, as already seen for the Sun. conclusions: The only two possible reasons for the discrepancy are a serious error in the oscillator strength of the NiI line blending the 630 nm line or the presence of an unknown blend in the 636 nm line, which makes the feature stronger. The CN lines blending the 636 nm line cannot be responsible for the discrepancy. The CaI autoionisation line, on the red wing of which the 636 nm line is formed, is not well modelled by our synthetic spectra. However, a better reproduction of this line would result in even higher abundances from the 636 nm, thus increasing the discrepancy.
The abundance of oxygen was determined for selected very metal-poor G-K stars (six giants and one turn-off star) based on the high S/N and high-resolution spectra observed with Keck HIRES in the red through near-IR region comprising the permitted O I lines (7771-5, 8446) along with the [O I] forbidden line at 6363 A. It turned out that both the abundances from the permitted line features, O I 7771-5 and O I 8446, agree quite well with each other, while the forbidden line yields somewhat discrepant and divergent abundances with a tendency of being underestimated on the average. The former (7773/8446) solution, which we believe to be more reliable, gives a fairly tight [O/Fe] vs. [Fe/H] relation such that increasing steadily from [O/Fe] = 0.6 (at [Fe/H] = -1.5) to [O/Fe] = 1.0 (at [Fe/H] = -3.0), in reasonable consistency with the trend recently reported based on the analysis of the UV OH lines. We would suspect that some kind of weakening mechanism may occasionally act on the formation of [O I] forbidden lines in metal-poor stars. Therefore, [O I] lines may not be so a reliable abundance indicator as has been generally believed.
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