We present evidence for mass segregation in the outer-halo globular cluster Palomar 14, which is intuitively unexpected since its present-day two-body relaxation time significantly exceeds the Hubble time. Based on archival Hubble Space Telescope imaging, we analyze the radial dependence of the stellar mass function in the clusters inner 39.2 pc in the mass range of 0.53-0.80 M_sun, ranging from the main-sequence turn-off down to a V-band magnitude of 27.1 mag. The mass function at different radii is well approximated by a power law and rises from a shallow slope of 0.6+/-0.2 in the clusters core to a slope of 1.6+/-0.3 beyond 18.6 pc. This is seemingly in conflict with the finding by Beccari et al. (2011), who interpret the clusters non-segregated population of (more massive) blue straggler stars, compared to (less massive) red giants and horizontal branch stars, as evidence that the cluster has not experienced dynamical segregation yet. We discuss how both results can be reconciled. Our findings indicate that the cluster was either primordially mass-segregated and/or used to be significantly more compact in the past. For the latter case, we propose tidal shocks as the mechanism driving the clusters expansion, which would imply that Palomar 14 is on a highly eccentric orbit. Conversely, if the cluster formed already extended and with primordial mass segregation, this could support an accretion origin of the cluster.
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