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Register a new userEntropy for Quantum Pure States and Its Dynamical Relaxation
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We construct a complete set of Wannier functions which are localized at both given positions and momenta. This allows us to introduce the quantum phase space, onto which a quantum pure state can be mapped unitarily. Using its probability distribution in quantum phase space, we define an entropy for a quantum pure state. We prove an inequality regarding the long time behavior of our entropys fluctuation. For a typical initial state, this inequality indicates that our entropy can relax dynamically to a maximized value and stay there most of time with small fluctuations. This result echoes the quantum H-theorem proved by von Neumann in [Zeitschrift fur Physik {bf 57}, 30 (1929)]. Our entropy is different from the standard von Neumann entropy, which is always zero for quantum pure states. According to our definition, a system always has bigger entropy than its subsystem even when the system is described by a pure state. As the construction of the Wannier basis can be implemented numerically, the dynamical evolution of our entropy is illustrated with an example.
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We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but is a single energy-eigenstate that satisfies the eigenstate-thermalization hypothesis (ETH). Our result is mathematically rigorous and based on the Lieb-Robinson bound, which gives the upper bound of the velocity of information propagation in many-body quantum systems. The entanglement entropy of a subsystem is shown connected to thermodynamic heat, highlighting the foundation of the information-thermodynamics link. We confirmed our theory by numerical simulation of hard-core bosons, and observed dynamical crossover from thermal fluctuations to bare quantum fluctuations. Our result reveals a universal scenario that the second law emerges from quantum mechanics, and can experimentally be tested by artificial isolated quantum systems such as ultracold atoms.
We reply to Comment by J. Gemmer, L. Knipschild, R. Steinigeweg (arXiv:1712.02128) on our paper Phys. Rev. Lett. 119, 100601 (2017).
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This work considers entropy generation and relaxation in quantum quenches in the Ising and $3$-state Potts spin chains. In the absence of explicit symmetry breaking we find universal ratios involving Renyi entropy growth rates and magnetisation relaxation for small quenches. We also demonstrate that the magnetisation relaxation rate provides an observable signature for the dynamical Gibbs effect which is a recently discovered characteristic non-monotonous behaviour of entropy growth linked to changes in the quasi-particle spectrum.
We provide a pure state formulation for hydrodynamic dynamics of isolated quantum many-body systems. A pure state describing quantum systems in local thermal equilibrium is constructed, which we call a local thermal pure quantum ($ell$TPQ) state. We show that the thermodynamic functional and the expectation values of local operators (including a real-time correlation function) calculated from the $ell$TPQ state converge to those from a local Gibbs ensemble in the large fluid-cell limit. As a numerical demonstration, we investigate a one-dimensional spin chain and observe the hydrodynamic relaxation obeying the Fouriers law. We further prove the second law of thermodynamics and the quantum fluctuation theorem, which are also validated numerically. The $ell$TPQ formulation gives a useful theoretical basis to describe the emergent hydrodynamic behavior of quantum many-body systems furnished with a numerical efficiency, being applicable to both the non-relativistic and relativistic regimes.
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