The structure of the nucleus 25F was investigated through in-beam {gamma}-ray spectroscopy of the fragmentation of 26Ne and 27,28Na ion beams. Based on the particle-{gamma} and particle-{gamma}{gamma} coincidence data, a level scheme was constructed and compared with shell model and coupled-cluster calculations. Some of the observed states were interpreted as quasi single-particle states built on top of the closed-shell nucleus 24O, while the others were described as states arising from coupling of a single proton to the 2+ core excitation of 24O.
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