Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userCrystal structure and physical properties of EuPtIn$_{4}$ intermetallic antiferromagnet
110
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We report the synthesis of EuPtIn$_{4}$ single crystalline platelets by the In-flux technique. This compound crystallizes in the orthorhombic Cmcm structure with lattice parameters $a=4.542(1)$ AA, $b=16.955(2)$ AA$,$ and $c=7.389(1)$ AA. Measurements of magnetic susceptibility, heat capacity, electrical resistivity, and electron spin resonance (ESR) reveal that EuPtIn$_{4}$ is a metallic Curie-Weiss paramagnet at high temperatures and presents antiferromagnetic (AFM) ordering below $T_{N}=13.3$ K. In addition, we observe a successive anomaly at $T^{*} = 12.6$ K and a spin-flop transition at $H_{c} sim 2.5$ T applied along the $ac$-plane. In the paramagnetic state, a single Eu$^{2+}$ Dysonian ESR line with a Korringa relaxation rate of $b = 4.1(2)$ Oe/K is observed. Interestingly, even at high temperatures, both ESR linewidth and electrical resistivity reveal a similar anisotropy. We discuss a possible common microscopic origin for the observed anisotropy in these physical quantities likely associated with an anisotropic magnetic interaction between Eu$^{2+}$ 4$f$ electrons mediated by conduction electrons.
rate research
Read More
In this work we report the physical properties of the new intermetallic compound TbRhIn5 investigated by means of temperature dependent magnetic susceptibility, electrical resistivity, heat-capacity and resonant x-ray magnetic diffraction experiments. TbRhIn5 is an intermetallic compound that orders antiferromagnetically at TN = 45.5 K, the highest ordering temperature among the existing RRhIn5 (1-1-5, R = rare earth) materials. This result is in contrast to what is expected from a de Gennes scaling along the RRhIn5 series. The X-ray resonant diffraction data below TN reveal a commensurate antiferromagnetic (AFM) structure with a propagation vector (1/2 0 1/2) and the Tb moments oriented along the c-axis. Strong (over two order of magnitude) dipolar enhancements of the magnetic Bragg peaks were observed at both Tb absorption edges LII and LIII, indicating a fairly high polarization of the Tb 5d levels. Using a mean field model including an isotropic first-neighbors exchange interaction J(R-R) and the tetragonal crystalline electrical field (CEF), we were able to fit our experimental data and to explain the direction of the ordered Tb-moments and the enhanced TN of this compound. The evolution of the magnetic properties along the RRhIn5 series and its relation to CEF effects for a given rare-earth is discussed.
In this work, we combined magnetization, pressure dependent electrical resistivity, heat-capacity, 63Cu Nuclear Magnetic Resonance (NMR) and X-ray resonant magnetic scattering experiments to investigate the physical properties of the intermetallic CeCuBi2 compound. Our single crystals show an antiferromagnetic ordering at TN ~ 16 K and the magnetic properties indicate that this compound is an Ising antiferromagnet. In particular, the low temperature magnetization data revealed a spin-flop transition at T = 5 K when magnetic fields about 5.5 T are applied along the c-axis. Moreover, the X-ray magnetic diffraction data below TN revealed a commensurate antiferromagnetic structure with propagation wavevector (0 0 1/2) with the Ce^3+ moments oriented along the c-axis. Furthermore, our heat capacity, pressure dependent resistivity and temperature dependent 63Cu NMR data suggest that CeCuBi2 exhibits a weak heavy fermion behavior with strongly localized Ce^3+ 4f electrons. We thus discuss a scenario taking into account the anisotropic magnetic interaction between the Ce^3+ ions along with the tetragonal crystalline electric field effects in CeCuBi2.
We present a method for producing high quality KCo2As2 crystals, stable in air and suitable for a variety of measurements. X-ray diffraction, magnetic susceptibility, electrical transport and heat capacity measurements confirm the high quality and an absence of long range magnetic order down to at least 2 K. Residual resistivity values approaching 0.25 $muOmega$~cm are representative of the high quality and low impurity content, and a Sommerfeld coefficient $gamma$ = 7.3 mJ/mol K$^2$ signifies weaker correlations than the Fe-based counterparts. Together with Hall effect measurements, angle-resolved photoemission experiments reveal a Fermi surface consisting of electron pockets at the center and corner of the Brillouin zone, in line with theoretical predictions and in contrast to the mixed carrier types of other pnictides with the ThCr2Si2 structure. A large, linear magnetoresistance of 200% at 14~T, together with an observed linear and hyperbolic, rather than parabolic, band dispersions are unusual characteristics of this metallic compound and may indicate more complex underlying behavior.
In this paper we report the structural and property (magnetic and electrical transport) measurements of nanocrystals of half-doped $mathrm{La_{0.5}Ca_{0.5}MnO_3}$(LCMO) synthesized by chemical route, having particle size down to an average diameter of 15nm. It was observed that the size reduction leads to change in crystal structure and the room temperature structure is arrested so that the structure does not evolve on cooling unlike bulk samples. The structural change mainly affects the orthorhombic distortion of the lattice. By making comparison with observed crystal structure data under hydrostatic pressure it is suggested that the change in the crystal structure of the nanocrystals occurs due to an effective hydrostatic pressure created by the surface pressure on size reduction. This not only changes the structure but also causes the room temperature structure to freeze-in. The size reduction also does not allow the long supercell modulation needed for the Charge Ordering, characteristic of this half-doped manganite, to set-in. The magnetic and transport measurements also show that the Charge Ordering (CO) does not occur when the size is reduced below a critical size. Instead, the nanocrystals show ferromagnetic ordering down to the lowest temperatures along with metallic type conductivity. Our investigation establishes a structural basis for the destabilization of CO state observed in half-doped manganite nanocrystals.
We report on the crystal structure, magnetic susceptibility, specific heat, electrical and thermoelectrical properties of AmPd5Al2, the americium counterpart of the unconventional superconductor NpPd5Al2. AmPd5Al2 crystallizes in the ZrNi2Al5-type of structure with lattice parameters: a = 4.1298 A and c = 14.7925 A. Magnetic measurements of AmPd5Al2 indicate a paramagnetic behavior with no hint of magnetic ordering nor superconductivity down to 2 K. This aspect is directly related to its 5f6 electronic configuration with J = 0. The specific heat measurements confirm the non magnetic ground state of this compound. The low temperature electronic specific heat gamma_el = 20 mJ mol-1K-2 is clearly enhanced as compared to americium metal. All transport measurements obtained point to a metallic behavior in AmPd5Al2.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
