To significantly improve the frequency references used in radio-astronomy and precision measurements in atomic physics, we provide frequency dissemination through a 642 km coherent optical fiber link, that will be also part of a forthcoming European network of optical links. We obtained a resolution of 3e-19 at 1000 s on the frequency transfer, and an accuracy of 5e-19. The ultimate link performance has been evaluated by doubling the link to 1284 km, demonstrating a new characterization technique based on the double round-trip on a single fiber. The arming of a second fiber is avoided: this is beneficial to long hauls realizations in view of a continental fiber network for frequency and time metrology. The data analysis is based on the Allan deviation; its expression is theoretically derived for the observed noise power spectrum, which is seldom found in the literature.
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