Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userDzyaloshinskii-Moriya nature of ferroelectric ordering in magnetoelectric Gd$_{1-x}$Y$_{x}$MnO$_{3}$ system
110
0
0.0
(
0
)
Added by
Joaquim Agostinho Moreira
Publication date
2014
fields
Physics
and research's language is
English
Ask ChatGPT about the research
No Arabic abstract
This work reports on magnetic, dielectric, thermodynamic and magnetoelectric properties of Gd$_{1-x}$Y$_{x}$MnO$_{3}$, with 0 leq x leq 0.4, with emphasis on the (x, T) phase diagram, towards unraveling the role of the driving mechanisms in stabilizing both magnetic and ferroelectric orderings. The (x, T) phase diagram reflects the effect of lattice distortions induced by the substitution of $Gd^{3+}$ ion by smaller $Y^{3+}$ ion, which gradually unbalances the antiferromagnetic against the ferromagnetic exchange interactions, enabling the emergence of ferroelectricity for higher concentrations of yttrium. For $x leq 0.1$, the paramagnetic phase is followed by a presumably incommensurate collinear antiferromagnetic phase, then a weak ferromagnetic canted A-type antiferromagnetic ordering is established at lower temperatures.For $0.2 leq x leq 0.4$, a different phase sequence is obtained. The canted A-type antiferromagnetic arrangement is no more stable, and instead a pure antiferromagnetic ordering is stabilized below T$_{lock}$ $approx$ 14 - 17 K, with an improper ferroelectric character. From these results, a cycloid modulated spin arrangement at low temperatures is proposed, accordingly to the inverse Dzyaloshinskii Moriya model. Anomalous temperature dependence of the dipolar relaxation energy and magnetization evidence for structural and magnetic changes occurring at $T* approx 22 - 28 K$, for $0.1 leq x leq 0.4$.
rate research
Read More
We explore the magnetically-ordered ground state of the isovalently-substituted Mott-insulator Y$_{1-x}$La$_{x}$TiO$_{3}$ for $x$ $leq$ 0.3 via single crystal growth, magnetometry, neutron diffraction, x-ray magnetic circular dichroism (XMCD), muon spin rotation ($mu$SR) and small-angle neutron scattering (SANS). We find that the decrease in the magnetic transition temperature on approaching the ferromagnetic (FM) - antiferromagnetic (AFM) phase boundary at the La concentration $x_c$ $approx$ 0.3 is accompanied by a strong suppression of both bulk and local ordered magnetic moments, along with a volume-wise separation into magnetically-ordered and paramagnetic regions. The thermal phase transition does not show conventional second-order behavior, since neither a clear signature of dynamic critical behavior nor a power-law divergence of the magnetic correlation length is found for the studied substitution range; this finding becomes increasingly obvious with substitution. Finally, from SANS and magnetometry measurements, we discern a crossover from easy-axis to easy-plane magneto-crystalline anisotropy with increasing La substitution. These results indicate complex changes in magnetic structure upon approaching the phase boundary.
We present a phenomenological theory for the ferromagnetic transition temperature, the magnetic susceptibility at high temperatures, and the structural distortion in the La$_{1-y}$(Ca$_{1-x}$Sr$_{x}$)$_{y}$MnO$_{3}$ system. We construct a Ginzburg-Landau free energy that describes the magnetic and the structural transitions, and a competition between them. The parameters of the magnetic part of the free energy are derived from a mean-field solution of the magnetic interaction for arbitrary angular momentum. The theory provides a qualitative description of the observed magnetic and structural phase transitions as functions of Sr-doping level ($x$) for $y=0.25$.
A laboratory hard X-ray photoelectron spectroscopy (HXPS) system equipped with a monochromatic Cr K$alpha$ ($h u = 5414.7$ eV) X-ray source was applied to an investigation of the core-level electronic structure of La$_{1-x}$Sr$_x$MnO$_3$. No appreciable high binding-energy shoulder in the O $1s$ HXPS spectra were observed while an enhanced low binding-energy shoulder structure in the Mn $2p_{3/2}$ HXPS spectra were observed, both of which are manifestation of high bulk sensitivity. Such high bulk sensitivity enabled us to track the Mn $2p_{3/2}$ shoulder structure in the full range of $x$, giving us a new insight into the binding-energy shift of the Mn $2p_{3/2}$ core level. Comparisons with the results using the conventional laboratory XPS ($h u = 1486.6$ eV) as well as those using a synchrotron radiation source ($h u = 7939.9$ eV) demonstrate that HXPS is a powerful and convenient tool to analyze the bulk electronic structure of a host of different compounds.
We present the electronic structure of Sr_{1-(x+y)}La_{x+y}Ti_{1-x}Cr_{x}O_{3} investigated by high-resolution photoemission spectroscopy. In the vicinity of Fermi level, it was found that the electronic structure were composed of a Cr 3d local state with the t_{2g}^{3} configuration and a Ti 3d itinerant state. The energy levels of these Cr and Ti 3d states are well interpreted by the difference of the charge-transfer energy of both ions. The spectral weight of the Cr 3d state is completely proportional to the spin concentration x irrespective of the carrier concentration y, indicating that the spin density can be controlled by x as desired. In contrast, the spectral weight of the Ti 3d state is not proportional to y, depending on the amount of Cr doping.
We studied for the first time the magnetic phase diagram of the rare-earth manganites series Gd$_{1-x}$Ca$_{x}$MnO$_{3}$ (GCMO) over the full concentration range based on density functional theory. GCMO has been shown to form solid solutions. We take into account this disordered character by adapting special quasi random structures at different concentration steps. The magnetic phase diagram is mainly described by means of the magnetic exchange interactions between the Mn sites and Monte Carlo simulations were performed to estimate the corresponding transition temperatures. They agree very well with recent experiments. The hole doped region $x<0.5$ shows a strong ferromagnetic ground state, which competes with A-type antiferromagnetism at higher Ca concentrations $x>0.6$.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
