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It is currently assumed that infrared dark clouds (IRDCs) represent the earliest evolutionary stages of high-mass stars ($>$ 8 M$_{odot}$). Submillimeter and millimeter-wave studies performed over the past 15 years show that IRDCs possess a broad variety of properties, and hence a wide range of problems and questions that can be tackled. In this paper, we report an investigation of the molecular composition and chemical processes in two groups of IRDCs. Using the Mopra, APEX, and IRAM radio telescopes over the last four years, we have collected molecular line data for CO, H$_2$CO, HNCO, CH$_3$CCH, CH$_3$OH, CH$_3$CHO, CH$_3$OCHO, and CH$_3$OCH$_3$. For all of these species we estimated molecular abundances. We then undertook chemical modeling studies, concentrating on the source IRDC028.34+0.06, and compared observed and modeled abundances. This comparison showed that to reproduce observed abundances of complex organic molecules (COMs), a 0-D gas-grain model with constant physical conditions is not sufficient. We achieved greater success with the use of a warm-up model, in which warm-up from 10 K to 30 K occurs following a cold phase.
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Massive stars play an important role in shaping the structure of galaxies. Infrared dark clouds (IRDCs), with their low temperatures and high densities, have been identified as the potential birthplaces of massive stars. In order to understand the formation processes of massive stars the physical and chemical conditions in infrared dark clouds have to be characterized. The goal of this paper is to investigate the chemical composition of a sample of southern infrared dark clouds. One important aspect of the observations is to check, if the molecular abuncances in IRDCs are similar to the low-mass pre-stellar cores, or whether they show signatures of more evolved evolutionary stages. We performed observations toward 15 IRDCs in the frequency range between 86 and 93 GHz using the 22-m Mopra radio telescope. We detect HNC, HCO$^+$ and HNC emission in all clouds and N$_2$H$^+$ in all IRDCs except one. In some clouds we detect SiO emission. Complicated shapes of the HCO$^+$ emission line profile are found in all IRDCs. Both signatures indicates the presence of infall and outflow motions and beginning of star formation activity, at least in some parts of the IRDCs. Where possible, we calculate molecular abundances and make a comparison with previously obtained values for low-mass pre-stellar cores and high-mass protostellar objects (HMPOs). We show a tendency for IRDCs to have molecular abundances similar to low-mass pre-stellar cores rather than to HMPOs abundances on the scale of our single-dish observations.
It is commonly assumed that cold and dense Infrared Dark Clouds (IRDCs) likely represent the birth sites massive stars. Therefore, this class of objects gets increasing attention. To enlarge the sample of well-characterised IRDCs in the southern hemisphere, we have set up a program to study the gas and dust of southern IRDCs. The present paper aims at characterizing the continuuum properties of this sample of objects. We cross-correlated 1.2 mm continuum data from SIMBA@SEST with Spitzer/GLIMPSE images to establish the connection between emission sources at millimeter wavelengths and the IRDCs we see at 8 $mu$m in absorption against the bright PAH background. Analysing the dust emission and extinction leads to a determination of masses and column densities, which are important quantities in characterizing the initial conditions of massive star formation. The total masses of the IRDCs were found to range from 150 to 1150 $rm M_odot$ (emission data) and from 300 to 1750 $rm M_odot$ (extinction data). We derived peak column densities between 0.9 and 4.6 $times 10^{22}$ cm$^{-2}$ (emission data) and 2.1 and 5.4 $times 10^{22}$ cm$^{-2}$ (extinction data). We demonstrate that the extinction method fails for very high extinction values (and column densities) beyond A$_{rm V}$ values of roughly 75 mag according to the Weingartner & Draine (2001) extinction relation $R_{rm V} = 5.5$ model B. The derived column densities, taking into account the spatial resolution effects, are beyond the column density threshold of 3.0 $times 10^{23}$ cm$^{-2}$ required by theoretical considerations for massive star formation. We conclude that the values for column densities derived for the selected IRDC sample make these objects excellent candidates for objects in the earliest stages of massive star formation.
Since the start of ALMA observatory operation, new and important chemistry of infrared cold core was revealed. Molecular transitions at millimeter range are being used to identify and to characterize these sources. We have investigated the 231 GHz ALMA archive observations of the infrared dark cloud region C9, focusing on the brighter source that we called as IRDC-C9 Main. We report the existence of two sub-structures on the continuum map of this source: a compact bright spot with high chemistry diversity that we labelled as core, and a weaker and extended one, that we labelled as tail. In the core, we have identified lines of the molecules OCS(19-18), $^{13}$CS(5-4) and CH$_{3}$CH$_{2}$CN, several lines of CH$_{3}$CHO and the k-ladder emission of $^{13}$CH$_{3}$CN.We report two different temperature regions: while the rotation diagram of CH$_{3}$CHO indicates a temperature of 25 K, the rotation diagram of $^{13}$CH$_{3}$CN indicates a warmer phase at temperature of $sim450$K. In the tail, only the OCS(19-18) and $^{13}$CS(5-4) lines were detected. We used the $Nautilus$ and the textsc{Radex} codes to estimate the column densities and the abundances. The existence of hot gas in the core of IRDC-C9 Main suggests the presence of a protostar, which is not present in the tail.
Infrared Dark Clouds appear to be the long sought population of cold and dense aggregations with the potential of harbouring the earliest stages of massive star formation. Up to now there has been no systematic study on the temperature distribution, velocity fields, chemical and physical state toward this new cloud population. Knowing these properties is crucial for understanding the presence, absence and the very potential of star formation. The present paper aims at addressing these questions. We analyse temperature structures and velocity fields and gain information on their chemical evolution. The gas emission is remarkably coextensive with the extinction seen at infrared wavelengths and with the submillimeter dust emission. Our results show that IRDCs are on average cold (T < 20 K) and have variations among the different cores. IRDC cores are in virial equilibrium, are massive (M > 100 M_sun), highly turbulent (1 -- 3 km/s) and exhibit significant velocity structure (variations around 1 -- 2 km/s over the cloud). We find an increasing trend in temperature from IRDCs with high ammonia column density to high mass protostellar objects and hot core/Ultracompact Hii regions stages of early warm high-mass star formation while linewidths of IRDCs are smaller. On the basis of this sample, we infer that while active star formation is not yet pervasive in most IRDCs, local condensations might collapse in the future or have already begun forming stars.
We investigate the infall properties in a sample of 11 infrared dark clouds (IRDCs) showing blue-asymmetry signatures in HCO$^{+}$ J=1--0 line profiles. We used JCMT to conduct mapping observations in HCO$^{+}$ J=4--3 as well as single-pointing observations in HCO$^{+}$ J =3--2, towards 23 clumps in these IRDCs. We applied the HILL model to fit these observations and derived infall velocities in the range of 0.5-2.7 km s$^{-1}$, with a median value of 1.0 km s$^{-1}$, and obtained mass accretion rates of 0.5-14$times$10$^{-3}$ Msun yr$^{-1}$. These values are comparable to those found in massive star forming clumps in later evolutionary stages. These IRDC clumps are more likely to form star clusters. HCO$^{+}$ J =3--2 and HCO$^{+}$ J =1--0 were shown to trace infall signatures well in these IRDCs with comparable inferred properties. HCO$^{+}$ J=4--3, on the other hand, exhibits infall signatures only in a few very massive clumps, due to smaller opacties. No obvious correlation for these clumps was found between infall velocity and the NH3/CCS ratio.
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