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Register a new userA Herschel Study of D/H in Water in the Jupiter-Family Comet 45P/Honda-Mrkos-Pajdusakova and Prospects for D/H Measurements with CCAT
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We present Herschel observations of water isotopologues in the atmosphere of the Jupiter-family comet 45P/Honda-Mrkos-Pajdusakova. No HDO emission is detected, with a 3 sigma upper limit of 2.0 10-4 for the D/H ratio. This value is consistent with the earlier Herschel measurement in the Jupiter-family comet 103P/Hartley 2. The canonical value of 3 10-4 measured pre-Herschel in a sample of Oort-cloud comets can be excluded at a 4.5 sigma level. The observations presented here further confirm that a diversity of D/H ratios exists in the comet population and emphasize the need for additional measurements with future ground-based facilities, such as CCAT, in the post-Herschel era.
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We report on photometry and imaging of the Jupiter Family Comets 41P/Tuttle-Giacobini-Kresak and 45P/Honda-Mrkos-Pajdusakova with the TRAPPIST-North telescope. We observed 41P on 34 nights from February 16, 2017 to July 27, 2017 pre- and post-perihelion (r$_h$=1.04 au), while we collected data for comet 45P from February 10 to March 30 after perihelion (r$_h$=0.53 au). We computed the production rates of the daughter species OH, NH, CN, C$_3$ and C$_2$ and we measured the dust proxy, Af$rho$, for both comets. The peak of water production rate of 41P was (3.46$pm$0.20)$times$10$^{27}$ molecules/s on April 3, 2017 when the comet was at 1.05 au from the Sun. We have shown that the activity of 41P is decreasing by about 30% to 40% from one apparition to the next. We measured a mean water production rate for 45P of (1.43$pm$0.62)$times$10$^{27}$ molecules/s during a month after perihelion. Our results show that these Jupiter Family Comets had low gas and dust activity and no outburst was detected. Relative abundances, expressed as ratios of production rates and Af$rho$ parameter with respect to OH and to CN, were compared to those measured in other comets. We found that 41P and 45P have a typical composition in term of carbon bearing species. The study of coma features exhibited by the CN gas species allowed the measurement of the rotation period of 41P, showing a surprisingly large increase of the rotation period from (30$pm$5) hrs at the end of March to (50$pm$10) hrs at the end of April, 2017 in agreement with recent observations by other teams.
Studying materials released from Jupiter-family comets (JFCs) as seen in their inner comae, the envelope of gas and dust forming as the comet approaches the Sun, provides an improved understanding of their origin and evolutionary history. As part of a coordinated, multi-wavelength observing campaign, we observed comet 45P/Honda-Mrkos-Pajduv{s}{a}kov{a} during its close approach to Earth in February 2017. Narrowband observations were taken using the Bok 90 telescope at KPNO on February 16 and 17 UT, revealing gas and dust structures. We observed different jet directions for different volatile species, implying source region heterogeneity, consistent with other ground-based as well as in situ observations of comet nuclei. A repeating feature visible in CN and C$_2$ images on February 16, was recovered on February 17 with an interval of $7.6pm0.1$ hours, consistent with the rotation period of the comet derived from Arecibo Observatory radar observations. The repeating features projected gas velocity away from the nucleus is 0.8 km/s, with an expansion velocity as 0.5 km/s. The amount of CN material released in one cycle has a lower limit of 11 kg, depending on composition, a quantity small enough to be produced by repeated exposure of nucleus ices to sunlight. This repeating CN jet forming within 400 km of the nucleus may be typical of inner coma behavior in JFCs. Similar repeating CN features could exist and be common in other observed comets, but obscured by other processes and daughter product species as viewed from distances further than the scale length of CN molecules.
The D/H ratio in cometary water is believed to be an important indicator of the conditions under which icy planetesimals formed and can provide clues to the contribution of comets to the delivery of water and other volatiles to Earth. Available measurements suggest that there is isotopic diversity in the comet population. The Herschel Space Observatory revealed an ocean-like ratio in the Jupiter-family comet 103P/Hartley 2, whereas most values measured in Oort-cloud comets are twice as high as the ocean D/H ratio. We present here a new measurement of the D/H ratio in the water of an Oort-cloud comet. HDO, H_2O, and H_2^18O lines were observed with high signal-to-noise ratio in comet C/2009 P1 (Garradd) using the Herschel HIFI instrument. Spectral maps of two water lines were obtained to constrain the water excitation. The D/H ratio derived from the measured H_2^16O and HDO production rates is 2.06+/-0.22 X 10**-4. This result shows that the D/H in the water of Oort-cloud comets is not as high as previously thought, at least for a fraction of the population, hence the paradigm of a single, archetypal D/H ratio for all Oort-cloud comets is no longer tenable. Nevertheless, the value measured in C/2009 P1 (Garradd) is significantly higher than the Earths ocean value of 1.558 X 10**-4. The measured H_2^16O/H_2^18O ratio of 523+/-32 is, however, consistent with the terrestrial value.
Herschel-PACS measurements of the rotational R(0) and R(1) HD lines in the atmospheres of Uranus and Neptune are analyzed in order to derive a D/H ratio with improved precision for both planets. The derivation of the D/H ratio includes also previous measurements of the R(2) line by the Short Wavelength Spectrometer on board the Infrared Space Observatory (ISO). The available spectroscopic line information of the three rotational transitions is discussed and applied in the radiative transfer calculations. The best simultaneous fit of all three lines requires only a minor departure from the Spitzer temperature profile of Uranus and a departure limited to 2K from the Voyager temperature profile of Neptune (both around the tropopause). The resulting and remarkably similar D/H ratios for Uranus and Neptune are found to be (4.4$pm$0.4)$times10^{-5}$ and (4.1$pm$0.4)$times10^{-5}$ respectively. Although the deuterium enrichment in both atmospheres compared to the protosolar value is confirmed, it is found to be lower compared to previous analysis. Using the interior models of Podolak et al. (1995), Helled et al. (2011) and Nettelmann et al. (2013), and assuming that complete mixing of the atmosphere and interior occured during the planets history, we derive a D/H in protoplanetary ices between (5.75--7.0)$times10^{-5}$ for Uranus and between (5.1--7.7)$times10^{-5}$ for Neptune. Conversely, adopting a cometary D/H for the protoplanetary ices between (15-30)$times10^{-5}$, we constrain the interior models of both planets to have an ice mass fraction of 14-32%, i.e. that the two planets are rock-dominated.
Deuterated molecules are important chemical tracers of prestellar and protostellar cores. Up to now, the titular reaction has been assumed to contribute to the generation of these deuterated molecules. We have measured the merged-beams rate coefficient for this reaction as function of the relative collision energy in the range of about 10 meV to 10 eV. By varying the internal temperature of the reacting H$_3^+$ molecules, we found indications for the existence of a reaction barrier. We have performed detailed theoretical calculations for the zero-point-corrected energy profile of the reaction and determined a new value for the barrier height of $approx$ 68 meV. Furthermore, we have calculated the tunneling probability through the barrier. Our experimental and theoretical results show that the reaction is essentially closed at astrochemically relevant temperatures. We derive a thermal rate coefficient of $<1times 10^{-12}$ cm$^3$ s$^{-1}$ for temperatures below 75 K with tunneling effects included and below 155 K without tunneling.
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