We discuss a limitation on extracting bounds on the scattering cross section of dark matter with nucleons, using neutrinos from the Sun. If the dark matter particle is sufficiently light (less than about 4 GeV), the effect of evaporation is not negligible and the capture process goes in equilibrium with the evaporation. In this regime, the flux of solar neutrinos of dark matter origin becomes independent of the scattering cross section and therefore no constraint can be placed on it. We find the minimum values of dark matter masses for which the scattering cross section on nucleons can be probed using neutrinos from the Sun. We also provide simple and accurate fitting functions for all the relevant processes of GeV-scale dark matter in the Sun.