We report on the temporally and spatially resolved detection of the precursory stages that lead to the formation of an unmagnetized, supercritical collision-less shock in a laser-driven laboratory experiment. The measured evolution of the electrostatic potential associated with the shock unveils the transition from a current free double layer into a symmetric shock structure, stabilized by ion reflection at the shock front. Supported by a matching Particle-In-Cell simulation and theoretical considerations, we suggest that this process is analogeous to ion reflection at supercritical collisionless shocks in supernova remnants.