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Register a new userDistribution of Entropy Production in a Single-Electron Box
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Recently, the fundamental laws of thermodynamics have been reconsidered for small systems. The discovery of the fluctuation relations has spurred theoretical and experimental studies on thermodynamics of systems with few degrees of freedom. The concept of entropy production has been extended to the microscopic level by considering stochastic trajectories of a system coupled to a heat bath. However, the experimental observation of the microscopic entropy production remains elusive. We measure distributions of the microscopic entropy production in a single-electron box consisting of two islands with a tunnel junction. The islands are coupled to separate heat baths at different temperatures, maintaining a steady thermal non-equilibrium. As Jarzynski equality between work and free energy is not applicable in this case, the entropy production becomes the relevant parameter. We verify experimentally that the integral and detailed fluctuation relations are satisfied. Furthermore, the coarse-grained entropy production from trajectories of electronic transitions is related to the bare entropy production by a universal formula. Our results reveal the fundamental roles of irreversible entropy production in non-equilibrium small systems.
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Computing the stochastic entropy production associated with the evolution of a stochastic dynamical system is a well-established problem. In a small number of cases such as the Ornstein-Uhlenbeck process, of which we give a complete exposition, the distribution of entropy production can be obtained analytically, but in general it is much harder. A recent development in solving the Fokker-Planck equation, in which the solution is written as a product of positive functions, enables the distribution to be obtained approximately, with the assistance of simple numerical techniques. Using examples in one and higher dimension, we demonstrate how such a framework is very convenient for the computation of stochastic entropy production in diffusion processes.
We study the entropy production rate in systems described by linear Langevin equations, containing mixed even and odd variables under time reversal. Exact formulas are derived for several important quantities in terms only of the means and covariances of the random variables in question. These include the total rate of change of the entropy, the entropy production rate, the entropy flux rate and the three components of the entropy production. All equations are cast in a way suitable for large-scale analysis of linear Langevin systems. Our results are also applied to different types of electrical circuits, which suitably illustrate the most relevant aspects of the problem.
We consider a system of two Brownian particles (say A and B), coupled to each other via harmonic potential of stiffness constant $k$. Particle-A is connected to two heat baths of constant temperatures $T_1$ and $T_2$, and particle-B is connected to a single heat bath of a constant temperature $T_3$. In the steady state, the total entropy production for both particles obeys the fluctuation theorem. We compute the total entropy production due to one of the particles called as partial or apparent entropy production, in the steady state for a time segment $tau$. When both particles are weakly interacting with each other, the fluctuation theorem for partial and apparent entropy production is studied. We find a significant deviation from the fluctuation theorem. The analytical results are also verified using numerical simulations.
A rigorous derivation of nonequilibrium entropy production via the path-integral formalism is presented. Entropy production is defined as the entropy change piled in a heat reservoir as a result of a nonequilibrium thermodynamic process. It is a central quantity by which various forms of the fluctuation theorem are obtained. The two kinds of the stochastic dynamics are investigated: the Langevin dynamics for an even-parity state and the Brownian motion of a single particle. Mathematical ambiguities in deriving the functional form of the entropy production, which depends on path in state space, are clarified by using a rigorous quantum mechanical approach.
We discuss the non-equilibrium properties of a thermally driven micromachine consisting of three spheres which are in equilibrium with independent heat baths characterized by different temperatures. Within the framework of a linear stochastic Langevin description, we calculate the time-dependent average irreversibility that takes a maximum value for a finite time. This time scale is roughly set by the spring relaxation time. The steady-state average entropy production rate is obtained in terms of the temperatures and the friction coefficients of the spheres. The average entropy production rate depends on thermal and/or mechanical asymmetry of a three-sphere micromachine. We also obtain the center of mass diffusion coefficient of a thermally driven three-sphere micromachine as a function of different temperatures and friction coefficients. With the results of the total entropy production rate and the diffusion coefficient, we finally discuss the efficiency of a thermally driven micromachine.
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