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Register a new userDetection of E-cyanomethanimine towards Sagittarius B2(N) in the Green Bank Telescope PRIMOS Survey
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The detection E-cyanomethanimine (E-HNCHCN) towards Sagittarius B2(N) is made by comparing the publicly available Green Bank Telescope (GBT) PRIMOS survey spectra (Hollis et al.) to laboratory rotational spectra from a reaction product screening experiment. The experiment uses broadband molecular rotational spectroscopy to monitor the reaction products produced in an electric discharge source using a gas mixture of NH3 and CH3CN. Several transition frequency coincidences between the reaction product screening spectra and previously unassigned interstellar rotational transitions in the PRIMOS survey have been assigned to E cyanomethanimine. A total of 8 molecular rotational transitions of this molecule between 9 and 50 GHz are observed with the GBT. E-cyanomethanimine, often called the HCN dimer, is an important molecule in prebiotic chemistry because it is a chemical intermediate in proposed synthetic routes of adenine, one of the two purine nucleobases found in DNA and RNA. New analyses of the rotational spectra of both E-cyanomethanimine and Z-cyanomethanimine that incorporate previous mm-wave measurements are also reported.
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The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, -1.2) times 10^13 cm-2 and a rotational temperature of 7.6 pm 1.5 K. This excitation temperature is significantly lower than that of the more stable cis conformer in the same source but is consistent with that of other complex molecular species recently detected in Sgr B2(N). The difference in the rotational temperatures of the two conformers suggests that they have different spatial distributions in this source. As the abundance of trans-methyl formate is far higher than would be expected if the cis and trans conformers are in thermodynamic equilibrium, processes that could preferentially form trans-methyl formate in this region are discussed. We also discuss measurements that could be performed to make this detection more certain. This manuscript demonstrates how publicly available broadband radio astronomical surveys of chemically rich molecular clouds can be used in conjunction with laboratory rotational spectroscopy to search for new molecules in the interstellar medium.
We report the first interstellar detection of DC$_7$N and six $^{13}$C-bearing isotopologues of HC$_7$N toward the dark cloud TMC-1 through observations with the Green Bank Telescope, and confirm the recent detection of HC$_5$$^{15}$N. For the average of the $^{13}$C isotopomers, DC$_7$N, and HC$_5$$^{15}$N, we derive column densities of 1.9(2)$times$10$^{11}$, 2.5(9)$times$10$^{11}$, and 1.5(4)$times$10$^{11}$ cm$^{-2}$, respectively. The resulting isotopic ratios are consistent with previous values derived from similar species in the source, and we discuss the implications for the formation chemistry of the observed cyanopolyynes. Within our uncertainties, no significant $^{13}$C isotopomer variation is found for HC$_7$N, limiting the significance CN could have in its production. The results further show that, for all observed isotopes, HC$_5$N may be isotopically depleted relative to HC$_3$N and HC$_7$N, suggesting that reactions starting from smaller cyanopolyynes may not be efficient to form HC$_{n}$N. This leads to the conclusion that the dominant production route may be the reaction between hydrocarbon ions and nitrogen atoms.
We present the methodology for ``blind millimetre-wave surveys for redshifted molecular absorption in the CO/HCO$^+$ rotational lines. The frequency range $30-50$ GHz appears optimal for such surveys, providing sensitivity to absorbers at $z gtrsim 0.85$. It is critical that the survey is ``blind, i.e. based on a radio-selected sample, including sources without known redshifts. We also report results from the first large survey of this kind, using the Q-band receiver on the Green Bank Telescope (GBT) to search for molecular absorption towards 36 sources, 3 without known redshifts, over the frequency range $39.6 - 49.5$ GHz. The GBT survey has a total redshift path of $Delta z approx 24$, mostly at $0.81 < z < 1.91$, and a sensitivity sufficient to detect equivalent ${rm H_2}$ column densities $gtrsim 3 times 10^{21}$ cm$^{-2}$ in absorption at $5sigma$ significance (using the CO-to-${rm H_2}$ and HCO$^+$-to-${rm H_2}$ conversion factors of the Milky Way). The survey yielded no confirmed detections of molecular absorption, yielding the $2sigma$ upper limit $n(z=1.2) < 0.15$ on the redshift number density of molecular gas at column densities $N({rm H_2}) gtrsim 3 times 10^{21}$ cm$^{-2}$.
A full spectral survey was carried out towards the Giant Molecular Cloud complex, Sagittarius B2 (Sgr B2), using the ISO Long Wavelength Spectrometer Fabry-Perot mode. This provided complete wavelength coverage in the range 47-196 um (6.38-1.53 THz) with a spectral resolution of 30-40 km/s. This is an unique dataset covering wavelengths inaccessible from the ground. It is an extremely important region of the spectrum as it contains both the peak of the thermal emission from dust, and crucial spectral lines of key atomic (OI, CII, OIII, NII and NIII) and molecular species (NH3, NH2, NH, H2O, OH, H3O+, CH, CH2, C3, HF and H2D+). In total, 95 spectral lines have been identified and 11 features with absorption depth greater than 3 sigma remain unassigned. Most of the molecular lines are seen in absorption against the strong continuum, whereas the atomic and ionic lines appear in emission (except for absorption in the OI 63 um and CII 158 um lines). Sgr B2 is located close to the Galactic Centre and so many of the features also show a broad absorption profile due to material located along the line of sight. A full description of the survey dataset is given with an overview of each detected species and final line lists for both assigned and unassigned features.
The Green Bank Telescope H II Region Discovery Survey (GBT HRDS) found hundreds of previously unknown Galactic regions of massive star formation by detecting hydrogen radio recombination line (RRL) emission from candidate H II region targets. Since the HRDS nebulae lie at large distances from the Sun, they are located in previously unprobed zones of the Galactic disk. Here we derive the properties of helium and carbon RRL emission from HRDS nebulae. Our target sample is the subset of the HRDS that has visible helium or carbon RRLs. This criterion gives a total of 84 velocity components (14% of the HRDS) with helium emission and 52 (9%) with carbon emission. For our highest quality sources, the average ionic He-4+/H+ abundance ratio by number, <y+>, is 0.068 +/- 0.023 (1-sigma). This is the same ratio as that measured for the sample of previously known Galactic H II regions. Nebulae without detected helium emission give robust y+ upper limits. There are 5 RRL emission components with y+ less than 0.04 and another 12 with upper limits below this value. These H II regions must have either a very low He-4 abundance or contain a significant amount of neutral helium. The HRDS has 20 nebulae with carbon RRL emission but no helium emission at its sensitivity level. There is no correlation between the carbon RRL parameters and the 8 microns mid-infrared morphology of these nebulae.
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