We discuss the exotic hadron structure and hadron-hadron interactions in view of heavy ion collisions. First, we demonstrate that a hadronic molecule with a large spatial size would be produced more abundantly in the coalescence model compared with the statistical model result. Secondly, we constrain the Lambda-Lambda interaction by using the recently measured Lambda-Lambda correlation data. We find that the RHIC-STAR data favor the Lambda-Lambda scattering parameters in the range 1/a_0 <= -0.8 fm^{-1} and r_{eff} >= 3 fm.
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