We study the observability for a heavy Majorana neutrino N along with a new charged gauge boson W at the LHC. We emphasize the complementarity of these two particles in their production and decay to unambiguously determine their properties. We show that the Majorana nature of N can be verified by the lepton-number violating like-sign dilepton process, and by polar and azimuthal angular distributions. The chirality of the W coupling to leptons and to quarks can be determined by a polar angle distribution in the reconstructed frame and an azimuthal angle distribution.