[Abridged] Classical novae (CNe) represent the main class of supersoft X-ray sources (SSSs) in the central region of our neighbouring galaxy M 31. Only three confirmed novae and three SSSs have been discovered in globular clusters (GCs) of any galaxy so far, of which one nova and two SSSs (including the nova) were found in M 31 GCs. To study the SSS state of CNe we carried out a high-cadence X-ray monitoring of the M 31 central area with XMM-Newton and Chandra. We analysed X-ray and optical data of a new transient X-ray source in the M 31 GC Bol 126, discovered serendipitously in Swift observations. Our optical data set was based on regular M 31 monitoring programmes from five different small telescopes. Additionally, we made use of Pan-STARRS 1 data obtained during the PAndromeda survey. Our observations reveal that the X-ray source in Bol 126 is the third SSS in an M 31 GC and can be confirmed as the second CN in the M 31 GC system. This nova is named M31N 2010-10f. Its properties in the X-ray and optical regimes agree with a massive white dwarf (M_WD >~ 1.3 M_sun) in the binary system. Incorporating the data on previously found (suspected) novae in M 31 GCs we used our high-cadence X-ray monitoring observations to estimate a tentative nova rate in the M 31 GC system of 0.05 /yr/GC. An optical estimate, based on the recent 10.5-year WeCAPP survey, gives a lower nova rate, which is compatible with the X-ray rate on the 95% confidence level. There is growing evidence that the nova rate in GCs is higher than expected from primordial binary formation and under conditions as in the field. Dynamical binary formation and/or additional accretion from the intracluster medium are possible scenarios for an increased nova rate, but observational confirmation for this enhancement has been absent, so far. Regular X-ray monitoring observations of M 31 provide a promising strategy to find these novae.
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