We determine the second Mellin moment of the isovector quark parton distribution function <x>_{u-d} from lattice QCD with N_f=2 sea quark flavours, employing the non-perturbatively improved Wilson-Sheikholeslami-Wohlert action at a pseudoscalar mass of 157(6) MeV. The result is converted non-perturbatively to the RI-MOM scheme and then perturbatively to the MSbar scheme at a scale mu = 2 GeV. As the quark mass is reduced we find the lattice prediction to approach the value extracted from experiments.