The properties of high energy density plasma are under increasing scrutiny in recent years due to their importance to our understanding of stellar interiors, the cores of giant planets$^{1}$, and the properties of hot plasma in inertial confinement fusion devices$^2$. When matter is heated by X-rays, electrons in the inner shells are ionized before the valence electrons. Ionization from the inside out creates atoms or ions with empty internal electron shells, which are known as hollow atoms (or ions)$^{3,4,5}$. Recent advances in free-electron laser (FEL) technology$^{6,7,8,9}$ have made possible the creation of condensed matter consisting predominantly of hollow atoms. In this Letter, we demonstrate that such exotic states of matter, which are very far from equilibrium, can also be formed by more conventional optical laser technology when the laser intensity approaches the radiation dominant regime$^{10}$. Such photon-dominated systems are relevant to studies of photoionized plasmas found in active galactic nuclei and X-ray binaries$^{11}$. Our results promote laser-produced plasma as a unique ultra-bright x-ray source for future studies of matter in extreme conditions as well as for radiography of biological systems and for material science studies$^{12,13,14,15}$.
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