We derive energy minima for biseparable states in three- and four-spin systems, with Heisenberg Hamiltonian and s <= 5/2. These provide lower bounds for tripartite and quadripartite entanglement in chains and rings with larger spin number N. We demonstrate that the ground state of an $N$-spin Heisenberg chain is $N$-partite entangled, and compute the energy gap with respect to biseparable states for N <= 8.
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