Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userTopographical fingerprints of many-body interference blocking in STM junctions on thin insulating films
168
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Negative differential conductance (NDC) is a non-linear transport phenomenon ubiquitous in molecular nanojunctions. Its physical origin can be the most diverse. In rotationally symmetric molecules with orbitally degenerate many-body states, it can be ascribed to interference effects. We establish in this paper a criterion to identify the interference blocking scenario by correlating the spectral and the topographical information achievable in an STM single molecule measurement. Simulations of current voltage characteristics and current maps for a Cu-Phthalocyanine (CuPc) on a thin insulating film are presented as experimentally relevant examples.
rate research
Read More
A microscopic theory of the transport in a scanning tunnelling microscope (STM) set-up is introduced for pi-conjugated molecules on insulating films, based on the density matrix formalism. A key role is played in the theory by the energy dependent tunnelling rates which account for the coupling of the molecule to the tip and to the substrate. In particular, we analyze how the geometrical differences between the localized tip and extended substrate are encoded in the tunnelling rate and influence the transport characteristics. Finally, using benzene as an example of a planar, rotationally symmetric molecule, we calculate the STM current voltage characteristics and current maps and analyze them in terms of few relevant angular momentum channels.
Most theoretical studies of nanoscale transport in molecular junctions rely on the combination of the Landauer formalism with Kohn-Sham density functional theory (DFT) using standard local and semilocal functionals to approximate exchange and correlation effects. In many cases, the resulting conductance is overestimated with respect to experiments. Recent works have demonstrated that this discrepancy may be reduced when including many-body corrections on top of DFT. Here we study benzene-dithiol (BDT) gold junctions and analyze the effect of many-body perturbation theory (MBPT) on the calculation of the conductance with respect to different bonding geometries. We find that the many-body corrections to the conductance strongly depend on the metal-molecule coupling strength. In the BDT junction with the lowest coupling, many-body corrections reduce the overestimation on the conductance to a factor two, improving the agreement with experiments. In contrast, in the strongest coupling cases, many-body corrections on the conductance are found to be sensibly smaller and standard DFT reveals a valid approach.
A magnetic material combining low losses and large Perpendicular Magnetic Anisotropy (PMA) is still a missing brick in the magnonic and spintronic fields. We report here on the growth of ultrathin Bismuth doped Y$_{3}$Fe$_{5}$O$_{12}$ (BiYIG) films on Gd$_{3}$Ga$_{5}$O$_{12}$ (GGG) and substituted GGG (sGGG) (111) oriented substrates. A fine tuning of the PMA is obtained using both epitaxial strain and growth induced anisotropies. Both spontaneously in-plane and out-of-plane magnetized thin films can be elaborated. Ferromagnetic Resonance (FMR) measurements demonstrate the high dynamic quality of these BiYIG ultrathin films, PMA films with Gilbert damping values as low as 3 10$^{-4}$ and FMR linewidth of 0.3 mT at 8 GHz are achieved even for films that do not exceed 30 nm in thickness. Moreover, we measure Inverse Spin Hall Effect (ISHE) on Pt/BiYIG stacks showing that the magnetic insulator$$s surface is transparent to spin current making it appealing for spintronic applications.
We study the pump-probe response of three insulating cuprates and develop a model for its recombination kinetics. The dependence on time, fluence, and both pump and probe photon energies imply many-body recombination on femtosecond timescales, characterized by anomalously large trapping and Auger coefficients. The fluence dependence follows a universal form that includes a characteristic volume scale, which we associate with the holon-doublon excitation efficiency. This volume varies strongly with pump photon energy and peaks near twice the charge-transfer energy, suggesting that the variation is caused by carrier multiplication through impact ionization.
The conductance of single molecule junctions is calculated using a Landauer approach combined to many-body perturbation theory MBPT) to account for electron correlation. The mere correction of the density-functional theory eigenvalues, which is the standard procedure for quasiparticle calculations within MBPT, is found not to affect noticeably the zero-bias conductance. To reduce it and so improve the agreement with the experiments, the wavefunctions also need to be updated by including the non-diagonal elements of the self-energy operator.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
