Hopf monoids from class functions on unitriangular matrices

We build, from the collection of all groups of unitriangular matrices, Hopf monoids in Joyals category of species. Such structure is carried by the collection of class function spaces on those groups, and also by the collection of superclass function spaces, in the sense of Diaconis and Isaacs. Superclasses of unitriangular matrices admit a simple description from which we deduce a combinatorial model for the Hopf monoid of superclass functions, in terms of the Hadamard product of the Hopf monoids of linear orders and of set partitions. This implies a recent result relating the Hopf algebra of superclass functions on unitriangular matrices to symmetric functions in noncommuting variables. We determine the algebraic structure of the Hopf monoid: it is a free monoid in species, with the canonical Hopf structure. As an application, we derive certain estimates on the number of conjugacy classes of unitriangular matrices.