We report the detection of thermal emission from the hot Jupiter WASP-3b in the KS band, using a newly developed guiding scheme for the WIRC instrument at the Palomar Hale 200in telescope. Our new guiding scheme has improved the telescope guiding precision by a factor of ~5-7, significantly reducing the correlated systematics in the measured light curves. This results in the detection of a secondary eclipse with depth of 0.181%pm0.020% (9-{sigma}) - a significant improvement in WIRCs photometric precision and a demonstration of the capability of Palomar/WIRC to produce high quality measurements of exoplanetary atmospheres. Our measured eclipse depth cannot be explained by model atmospheres with heat redistribution but favor a pure radiative equilibrium case with no redistribution across the surface of the planet. Our measurement also gives an eclipse phase center of 0.5045pm0.0020, corresponding to an ecos{omega} of 0.0070pm0.0032. This result is consistent with a circular orbit, although it also suggests the planets orbit might be slightly eccentric. The possible non-zero eccentricity provides insight into the tidal circularization process of the star-planet system, but also might have been caused by a second low-mass planet in the system, as suggested by a previous transit timing variation study. More secondary eclipse observations, especially at multiple wavelengths, are necessary to determine the temperature-pressure profile of the planetary atmosphere and shed light on its orbital eccentricity.
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