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Register a new userFormation of surface nanobubbles and universality of their contact angles: A molecular dynamics approach
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We study surface nanobubbles using molecular dynamics simulation of ternary (gas, liquid, solid) systems of Lennard-Jones fluids. They form for sufficiently low gas solubility in the liquid, i.e., for large relative gas concentration. For strong enough gas-solid attraction, the surface nanobubble is sitting on a gas layer, which forms in between the liquid and the solid. This gas layer is the reason for the universality of the contact angle, which we calculate from the microscopic parameters. Under the present equilibrium conditions the nanobubbles dissolve within less of a microsecond, consistent with the view that the experimentally found nanobubbles are stabilized by a nonequilibrium mechanism.
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The contact angle that a liquid drop makes on a soft substrate does not obey the classical Youngs relation, since the solid is deformed elastically by the action of the capillary forces. The finite elasticity of the solid also renders the contact angles different from that predicted by Neumanns law, which applies when the drop is floating on another liquid. Here we derive an elasto-capillary model for contact angles on a soft solid, by coupling a mean-field model for the molecular interactions to elasticity. We demonstrate that the limit of vanishing elastic modulus yields Neumanns law or a slight variation thereof, depending on the force transmission in the solid surface layer. The change in contact angle from the rigid limit (Young) to the soft limit (Neumann) appears when the length scale defined by the ratio of surface tension to elastic modulus $gamma/E$ reaches a few molecular sizes.
We investigate universality of the Eulerian velocity structure functions using velocity fields obtained from the stereoscopic particle image velocimetry (SPIV) technique in experiments and the direct numerical simulations (DNS) of the Navier-Stokes equations. We show that the numerical and experimental velocity structure functions up to order 9 follow a log-universality; we find that they collapse on a universal curve, if we use units that include logarithmic dependence on the Reynolds number. We then investigate the meaning and consequences of such log-universality, and show that it is connected with the properties of a multifractal free energy, based on an analogy between multifractal and themodynamics. We show that in such a framework, the existence of a fluctuating dissipation scale is associated with a phase transition describing the relaminarisation of rough velocity fields with different Holder exponents. Such a phase transition has been already observed using the Lagrangian velocity structure functions, but was so far believed to be out of reach for the Eulerian data.
The nonlinear dynamics of the free surface of an ideal conducting liquid in a strong external electric field is studied. It is establish that the equations of motion for such a liquid can be solved in the approximation in which the surface deviates from a plane by small angles. This makes it possible to show that on an initially smooth surface for almost any initial conditions points with an infinite curvature corresponding to branch points of the root type can form in a finite time.
Formation, evolution, and vanishing of bubbles are common phenomena in our nature, which can be easily observed in boiling or falling waters, carbonated drinks, gas-forming electrochemical reactions, etc. However, the morphology and the growth dynamics of the bubbles at nanoscale have not been fully investigated owing to the lack of proper imaging tools that can visualize nanoscale objects in liquid phase. Here we demonstrate, for the first time, that the nanobubbles in water encapsulated by graphene membrane can be visualized by in situ ultrahigh vacuum transmission electron microscopy (UHV-TEM), showing the critical radius of nanobubbles determining its unusual long-term stability as well as two distinct growth mechanisms of merging nanobubbles (Ostwald ripening and coalescing) depending on their relative sizes. Interestingly, the gas transport through ultrathin water membranes at nanobubble interface is free from dissolution, which is clearly different from conventional gas transport that includes condensation, transmission and evaporation. Our finding is expected to provide a deeper insight to understand unusual chemical, biological and environmental phenomena where nanoscale gas-state is involved.
The field of plasmonic nanobubbles, referring to bubbles generated around nanoparticles due to plasmonic heating, is growing rapidly in recent years. Theoretical, simulation and experimental studies have been reported to reveal the fundamental physics related to this nanoscale multi-physics phenomenon. Using plasmonic nanobubbles for applications is in the early stage but progressing. In this article, we briefly review the current state of this research field and give our perspectives on the research needs in the theoretical, simulation and experimental fronts. We also give our perspectives on how the fundamental understanding can be applied to more practical applications.
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