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Register a new userChemistry in Cosmic-Ray Dominated Regions (CRDRs)
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Molecular line observations may serve as diagnostics of the degree to which the number density of cosmic ray protons, having energies of 10s to 100s of MeVs each, is enhanced in starburst galaxies and galaxies with active nuclei. Results, obtained with the UCL_PDR code, for the fractional abundances of molecules as functions of the cosmic-ray induced ionisation rate, $zeta$, are presented. The aim is not to model any particular external galaxies. Rather, it is to identify characteristics of the dependencies of molecular abundances on $zeta$, in part to enable the development of suitable observational programmes for cosmic ray dominated regions (CRDRs) which will then stimulate detailed modelling. For a number density of hydrogen nuclei of of $10^4$ cm$^{-3}$, and high visual extinction, the fractional abundances of some species increase as $zeta$ increases to $10^{-14}$ s$^{-1}$, but for much higher values of $zeta$ the fractional abundances of all molecular species are significantly below their peak values. We show in particular that OH, H$_{2}$O, H$_{3}^{+}$, H$_{3}$O$^{+}$ and OH$^{+}$ attain large fractional abundances ($geqslant 10^{-8}$) for $zeta$ as large as $10^{-12}$ s$^{-1}$. HCO$^{+}$ is a poor tracer of CRDRs when $zeta > 10^{-13}$ s$^{-1}$. Sulphur-bearing species may be useful tracers of CRDRs gas in which $zeta sim 10^{-16}$ s$^{-1}$. Ammonia has a large fractional abundance for $zeta leqslant 10^{-16}$ s$^{-1}$ and nitrogen appears in CN-bearing species at significant levels as $zeta$ increases, even up to $sim 10^{-14}$ s$^{-1}$. In this paper, we also discuss our model predictions, comparing them to recent detections in both galactic and extragalactic sources. We show that they agree well, to a first approximation, with the observational constraints.
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We present a detailed theoretical study of the rotational excitation of CH$^+$ due to reactive and nonreactive collisions involving C$^+(^2P)$, H$_2$, CH$^+$, H and free electrons. Specifically, the formation of CH$^+$ proceeds through the reaction between C$^+(^2P)$ and H$_2( u_{rm H_2}=1, 2)$, while the collisional (de)excitation and destruction of CH$^+$ is due to collisions with hydrogen atoms and free electrons. State-to-state and initial-state-specific rate coefficients are computed in the kinetic temperature range 10-3000~K for the inelastic, exchange, abstraction and dissociative recombination processes using accurate potential energy surfaces and the best scattering methods. Good agreement, within a factor of 2, is found between the experimental and theoretical thermal rate coefficients, except for the reaction of CH$^+$ with H atoms at kinetic temperatures below 50~K. The full set of collisional and chemical data are then implemented in a radiative transfer model. Our Non-LTE calculations confirm that the formation pumping due to vibrationally excited H$_2$ has a substantial effect on the excitation of CH$^+$ in photon-dominated regions. In addition, we are able to reproduce, within error bars, the far-infrared observations of CH$^+$ toward the Orion Bar and the planetary nebula NGC~7027. Our results further suggest that the population of $ u_{rm H_2}=2$ might be significant in the photon-dominated region of NGC~7027.
Aims: We aim at deriving the excitation conditions of the interstellar gas as well as the local FUV intensities in the molecular cloud surrounding NGC 3603 to get a coherent picture of how the gas is energized by the central stars. Methods: The NANTEN2-4m submillimeter antenna is used to map the [CI] 1-0, 2-1 and CO 4-3, 7-6 lines in a 2 x 2 region around the young OB cluster NGC 3603 YC. These data are combined with C18O 2-1 data, HIRES-processed IRAS 60 and 100 micron maps of the FIR continuum, and Spitzer/IRAC maps. Results: The NANTEN2 observations show the presence of two molecular clumps located south-east and south-west of the cluster and confirm the overall structure already found by previous CS and C18O observations. We find a slight position offset of the peak intensity of CO and [CI], and the atomic carbon appears to be further extended compared to the molecular material. We used the HIRES far-infrared dust data to derive a map of the FUV field heating the dust. We constrain the FUV field to values of chi = 3 - 6 times 10^3 in units of the Draine field across the clouds. Approximately 0.2 to 0.3 % of the total FUV energy is re-emitted in the [CII] 158 {mu}m cooling line observed by ISO. Applying LTE and escape probability calculations, we derive temperatures (TMM1 = 43 K, TMM2 = 47 K), column densities (N(MM1) = 0.9 times 10^22 cm^-2, N(MM2) = 2.5 times 10^22 cm^-2) and densities (n(MM1) = 3 times 10^3 cm^-3, n(MM2) = 10^3 -10^4 cm^-3) for the two observed molecular clumps MM1 and MM2. Conclusions: The cluster is strongly interacting with the ambient molecular cloud, governing its structure and physical conditions. A stability analysis shows the existence of gravitationally collapsing gas clumps which should lead to star formation. Embedded IR sources have already been observed in the outskirts of the molecular cloud and seem to support our conclusions.
Water is the main constituent of interstellar ices, and it plays a key role in the evolution of many regions of the interstellar medium, from molecular clouds to planet-forming disks. In cold regions of the ISM, water is expected to be completely frozen out onto the dust grains. Nonetheless, observations indicate the presence of cold water vapor, implying that non-thermal desorption mechanisms are at play. Photodesorption by UV photons has been proposed to explain these observations, with the support of extensive experimental and theoretical work on ice analogues. In contrast, photodesorption by X-rays, another viable mechanism, has been little studied. The potential of this process to desorb key molecules, such as water, intact rather than fragmented or ionised, remains unexplored. We experimentally investigated X-ray photodesorption from water ice, monitoring all desorbing species. We find that desorption of neutral water is efficient, while ion desorption is minor. We derive for the first time yields that can be implemented in astrochemical models. These results open up the possibility of taking into account the X-ray photodesorption process in the modelling of protoplanetary disks or X-ray dominated regions.
We study the impact of cosmic rays (CRs) on the structure of virial shocks, using a large suite of high-resolution cosmological FIRE-2 simulations accounting for CR injection by supernovae. In massive ($M_{rm halo} gtrsim 10^{11},M_{odot}$), low-redshift ($zlesssim 1-2$) halos, which are expected to form hot halos with slowly-cooling gas in quasi-hydrostatic equilibrium (with a stable virial shock), our simulations without CRs do exhibit clear virial shocks. The cooler phase condensing out from inflows becomes pressure-confined to over-dense clumps, embedded in low-density, volume-filling hot gas whose cooling time is much longer than inflow time. The gas thus transitions sharply from cool free-falling inflow, to hot and thermal-pressure supported at approximately the virial radius ($approx R_{rm vir}$), and the shock is quasi-spherical. With CRs, we previously argued that halos in this particular mass and redshift range build up CR-pressure-dominated gaseous halos. Here, we show that when CR pressure dominates over thermal pressure, there is no significant virial shock. Instead, inflowing gas is gradually decelerated by the CR pressure gradient and the gas is relatively subsonic out to and even beyond $R_mathrm{vir}$. Rapid cooling also maintains sub-virial temperatures in the inflowing gas within $sim R_mathrm{vir}$.
We study the formation and evolution of the cosmic web, using the high-resolution CosmoGrid $Lambda$CDM simulation. In particular, we investigate the evolution of the large-scale structure around void halo groups, and compare this to observations of the VGS-31 galaxy group, which consists of three interacting galaxies inside a large void. The structure around such haloes shows a great deal of tenuous structure, with most of such systems being embedded in intra-void filaments and walls. We use the Nexus+ algorithm to detect walls and filaments in CosmoGrid, and find them to be present and detectable at every scale. The void regions embed tenuous walls, which in turn embed tenuous filaments. We hypothesize that the void galaxy group of VGS-31 formed in such an environment.
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