No Arabic abstract
An attempt to shed light on the various belief/idea systems in high Tc superconductivity that are at present popular. This text is in first instance intended to serve both string theorists and junior condensed matter physicists who want to enter this field. It departs from the premise that the often confusing, mutually contradicting portfolio of theories can be best appreciated by viewing it from a historical perspective. The histories of the following subjects are chronicled: the spin fluctuation superglue, Mottness, Resonating Valence Bonds and the gauge theories, pseudo-gap and competing orders, quantum critical metals. The author is well aware that any attempt to write such a history is subjective and comments are welcomed.
In the last two decades there have been tremendous attempts to built an adequate theory of high-temperature superconductivity. Most studies (including our efforts) used some model Hamiltonians with input parameters not directly related to the material. The dielectric response function of electrons in strongly correlated high-temperature superconductors is apriori unknown. Hence one has to start with the generic Hamiltonian including unscreened Coulomb and Froehlich electron-phonon interactions operating on the same scale since any ad-hoc assumption on their range and relative magnitude might fail. Using such a generic Hamiltonian I have built the analytical theory of high-temperature superconductivity in doped polar insulators predicting the critical temperature in excess of a hundred Kelvin without any adjustable parameters. The many-particle electron system is described by an analytically solvable polaronic t-Jp Hamiltonian with reduced hopping integral, t, allowed double on-site occupancy, large phonon-induced antiferromagnetic exchange, Jp >> t, and a high-temperature superconducting state of small superlight bipolarons protected from clustering.
We review application of the SU(4) model of strongly-correlated electrons to cuprate and iron-based superconductors. A minimal self-consistent generalization of BCS theory to incorporate antiferromagnetism on an equal footing with pairing and strong Coulomb repulsion is found to account systematically for the major features of high-temperature superconductivity, with microscopic details of the parent compounds entering only parametrically. This provides a systematic procedure to separate essential from peripheral, suggesting that many features exhibited by the high-$Ttsub c$ data set are of interest in their own right but are not central to the superconducting mechanism. More generally, we propose that the surprisingly broad range of conventional and unconventional superconducting and superfluid behavior observed across many fields of physics results from the systematic appearance of similar algebraic structures for the emergent effective Hamiltonians, even though the microscopic Hamiltonians of the corresponding parent states may differ radically from each other.
Soon after the discovery of the first high temperature superconductor by Georg Bednorz and Alex Mueller in 1986 the late Sir Nevill Mott answering his own question Is there an explanation? [Nature v 327 (1987) 185] expressed a view that the Bose-Einstein condensation (BEC) of small bipolarons, predicted by us in 1981, could be the one. Several authors then contemplated BEC of real space tightly bound pairs, but with a purely electronic mechanism of pairing rather than with the electron-phonon interaction (EPI). However, a number of other researchers criticized the bipolaron (or any real-space pairing) scenario as incompatible with some angle-resolved photoemission spectra (ARPES), with experimentally determined effective masses of carriers and unconventional symmetry of the superconducting order parameter in cuprates. Since then the controversial issue of whether the electron-phonon interaction (EPI) is crucial for high-temperature superconductivity or weak and inessential has been one of the most challenging problems of contemporary condensed matter physics. Here I outline some developments in the bipolaron theory suggesting that the true origin of high-temperature superconductivity is found in a proper combination of strong electron-electron correlations with a significant finite-range (Froehlich) EPI, and that the theory is fully compatible with the key experiments.
Recent experiments in the cuprates have seen evidence of a transient superconducting state upon optical excitation polarized along the c-axis [R. Mankowsky et al., Nature 516, 71 (2014)]. Motivated by these experiments we propose an extension of the single-layer $t-J-V$ model of cuprates to three dimensions in order to study the effects of inter-plane tunneling on the competition between superconductivity and bond density wave order. We find that an optical pump can suppress the charge order and simultaneously enhance superconductivity, due to the inherent competition between the two. We also provide an intuitive picture of the physical mechanism underlying this effect. Furthermore, based on a simple Floquet theory we estimate the magnitude of the enhancement.
Superconductivity in organic conductors is often tuned by the application of chemical or external pressure. With this type of tuning, orbital overlaps and electronic bandwidths are manipulated, whilst the properties of the molecular building blocks remain virtually unperturbed.Here, we show that the excitation of local molecular vibrations in the charge-transfer salt $kappa-(BEDT-TTF)_2Cu[N(CN)_2]Br$ induces a colossal increase in carrier mobility and the opening of a superconducting-like optical gap. Both features track the density of quasi-particles of the equilibrium metal, and can be achieved up to a characteristic coherence temperature $T^* approxeq 50 K$, far higher than the equilibrium transition temperature $T_C = 12.5 K$. Notably, the large optical gap achieved by photo-excitation is not observed in the equilibrium superconductor, pointing to a light induced state that is different from that obtained by cooling. First-principle calculations and model Hamiltonian dynamics predict a transient state with long-range pairing correlations, providing a possible physical scenario for photo-molecular superconductivity.