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Register a new userNon-Equilibrium Fluctuation-Dissipation Inequality and Non-Equilibrium Uncertainty Principle
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The fluctuation-dissipation relation is usually formulated for a system interacting with a heat bath at finite temperature in the context of linear response theory, where only small deviations from the mean are considered. We show that for an open quantum system interacting with a non-equilibrium environment, where temperature is no longer a valid notion, a fluctuation-dissipation inequality exists. Clearly stated, quantum fluctuations are bounded below by quantum dissipation, whereas classically the fluctuations can be made to vanish. The lower bound of this inequality is exactly satisfied by (zero-temperature) quantum noise and is in accord with the Heisenberg uncertainty principle, both in its microscopic origins and its influence upon systems. Moreover, it is shown that the non-equilibrium fluctuation-dissipation relation determines the non-equilibrium uncertainty relation in the weak-damping limit.
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We review generalized Fluctuation-Dissipation Relations which are valid under general conditions even in ``non-standard systems, e.g. out of equilibrium and/or without a Hamiltonian structure. The response functions can be expressed in terms of suitable correlation functions computed in the unperperturbed dynamics. In these relations, typically one has nontrivial contributions due to the form of the stationary probability distribution; such terms take into account the interaction among the relevant degrees of freedom in the system. We illustrate the general formalism with some examples in non-standard cases, including driven granular media, systems with a multiscale structure, active matter and systems showing anomalous diffusion.
We give a simple recipe for computing dissipation and fluctuations (commutator and anti-commutator correlation functions) for non-equilibrium black hole geometries. The recipe formulates Hawking radiation as an initial value problem, and is suitable for numerical work. We show how to package the fluctuation and dissipation near the event horizon into correlators on the stretched horizon. These horizon correlators determine the bulk and boundary field theory correlation functions. In addition, the horizon correlators are the components of a horizon effective action which provides a quantum generalization of the membrane paradigm. In equilibrium, the analysis reproduces previous results on the Brownian motion of a heavy quark. Out of equilibrium, Wigner transforms of commutator and anti-commutator correlation functions obey a fluctuation-dissipation relation at high frequency.
We derive a Bell-like inequality involving all correlations in local observables with uncertainty free states and show that the inequality is violated in quantum mechanics for EPR and GHZ states. If the uncertainties are allowed in local observables then the statistical predictions of hidden variable theory is well respected in quantum world. We argue that the uncertainties play a key role in understanding the non-locality issues in quantum world. Thus we can not rule out the possibility that a local, realistic hidden variable theory with statistical uncertainties in the observables might reproduce all the results of quantum theory.
Life has most likely originated as a consequence of processes taking place in non-equilibrium conditions (textit{e.g.} in the proximity of deep-sea thermal vents) selecting states of matter that would have been otherwise unfavorable at equilibrium. Here we present a simple chemical network in which the selection of states is driven by the thermodynamic necessity of dissipating heat as rapidly as possible in the presence of a thermal gradient: states participating to faster reactions contribute the most to the dissipation rate, and are the most populated ones in non-equilibrium steady-state conditions. Building upon these results, we show that, as the complexity of the chemical network increases, the textit{velocity} of the reaction path leading to a given state determines its selection, giving rise to non-trivial localization phenomena in state space. A byproduct of our studies is that, in the presence of a temperature gradient, thermophoresis-like behavior inevitably appears depending on the transport properties of each individual state, thus hinting at a possible microscopic explanation of this intriguing yet still not fully understood phenomenon.
By generalizing the traditional concept of heat dQ and work dW to also include their time-dependent irreversible components d_{i}Q and d_{i}W allows us to express them in terms of the instantaneous internal temperature T(t) and pressure P(t), whereas the conventional form uses the constant values T_{0} and P_{0} of the medium. This results in an extremely useful formulation of non-equilibrium thermodynamics so that the first law turns into the Gibbs fundamental relation and the Clausius inequality becomes an equality ointdQ(t)/T(t)equiv0 in all cases, a quite remarkable but unexpected result. We determine the irreversible components d_{i}Qequivd_{i}W and discuss how they can be determined to obtain the generalized dW(t) and dQ(t).
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