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Register a new userDistinguishability and Chiral Stability: Effects of Decoherence and Intermolecular Interactions
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We examine the effect of decoherence and intermolecular interactions (chiral discrimination energies) on the chiral stability and the distinguishability of initially pure versus mixed states in an open chiral system. Under a two-level approximation for a system, intermolecular interactions are introduced by a mean-field theory, and interaction between a system and an environment is modeled by a continuous measurement of a population difference between the two chiral states. The resultant equations are explored for various parameters, with emphasis on the combined effects of the initial condition of the system, the chiral discrimination energy and the decoherence. We focus on factors affecting the distinguishability as measured by population difference between the initially pure and mixed states and on the chiral stability as measured by the purity decay.
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We examine how initial coherences in open chiral systems affect distinguishability of pure versus mixed states and purity decay. Interaction between a system and an environment is modeled by a continuous position measurement and a two-level approximation is taken for the system. The resultant analytical solution is explored for various parameters, with emphasis on the interplay of initial coherences of the system and dephasing rate in determining the purity decay and differences in the time evolution of pure vs. mixed initial states. %the distinguishability and the decoherence process. Implications of the results on several fundamental problems are noted.
The physical origin of the so-called chirality-induced spin selectivity (CISS) effect has puzzled experimental and theoretical researchers over the past few years. Early experiments were interpreted in terms of unconventional spin-orbit interactions mediated by the helical geometry. However, more recent experimental studies have clearly revealed that electronic exchange interactions also play a key role in the magnetic response of chiral molecules in singlet states. In this investigation, we use spin-polarized closed shell density functional theory calculations to address the influence of exchange contributions to the interaction between helical molecules as well as of helical molecules with magnetized substrates. We show that exchange effects result in differences in the interaction properties with magnetized surfaces, shedding light into the possible origin of two recent important experimental results: enantiomer separation and magnetic exchange force microscopy with AFM tips functionalized with helical peptides.
We study theoretically and experimentally the infrared (IR) spectrum of an adamantane monolayer on a Au(111) surface. Using a new STM-based IR spectroscopy technique (IRSTM) we are able to measure both the nanoscale structure of an adamantane monolayer on Au(111) as well as its infrared spectrum, while DFT-based ab initio calculations allow us to interpret the microscopic vibrational dynamics revealed by our measurements. We find that the IR spectrum of an adamantane monolayer on Au(111) is substantially modified with respect to the gas-phase IR spectrum. The first modification is caused by the adamantane--adamantane interaction due to monolayer packing and it reduces the IR intensity of the 2912 cm$^{-1}$ peak (gas phase) by a factor of 3.5. The second modification originates from the adamantane--gold interaction and it increases the IR intensity of the 2938 cm$^{-1}$ peak (gas phase) by a factor of 2.6, and reduces its frequency by 276 cm$^{-1}$. We expect that the techniques described here can be used for an independent estimate of substrate effects and intermolecular interactions in other diamondoid molecules, and for other metallic substrates.
Distinguishability and predictability are part of complementarity relations which apply to two different kinds of interference experiments, with and without a path-detector, respectively. In [Opt. Comm. 179, 337 (2000)], Englert and Bergou pointed out the possible connection between distinguishability, predictability, and entanglement. They even conjectured that an entanglement measure was hidden between the measures of distinguishability and predictability. Here, we push forward this conjecture. We start defining a new entropic distinguishability measure and suggesting an entanglement measure as the difference between this entropic distinguishability and an entropic predictability measure already defined in the literature. Besides, we prove that it is possible to define an entanglement monotone from the largest value of the distinguishability and the corresponding predictability, provided that the predictability satisfy the criteria already established in the literature. Thus, this result formally connects an entanglement monotone with distinguishability and the corresponding predictability, without appealing to specific measures.
We address the time evolution of the quantum correlations ($QCs$) such as entanglement, purity, and coherence for a model of two non-interacting qubits initially prepared as a maximally entangled bipartite state. We contrast the comparative potential of the classical fields to preserve these $QCs$ in the noisy and noiseless realms. We also disclose the characteristic dynamical behavior of the $QCs$ of the two-qubit state under the static noisy effects originating from the common and different configuration models. We show that there is a direct connection between the fluctuations allowed by an environment and the $QCs$ preservation. Due to the static noisy dephasing effects, the $QCs$ are suppressed, resulting in the separability of the two-qubit entangled state after a finite duration. Here, the $QCs$ decay effects are found much smaller in the common configuration model than that of the opponent. Furthermore, this protection of the $QCs$ under static noise for large intervals is entirely attributable to the existence of the entanglement sudden death and birth phenomenon. Most importantly, we found the bipartite $QCs$ less fragile than the tripartite ones in comparison under the static noise. In the case of the measures, the concurrence is found to be sharper for showing the entanglement sudden death and birth revivals in comparison to the purity and decoherence.
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