The present paper deals with the question of representability of nets of C*-algebras whose underlying poset, indexing the net, is not upward directed. A particular class of nets, called C*-net bundles, is classified in terms of C*-dynamical systems having as group the fundamental group of the poset. Any net of C*-algebras embeds into a unique C*-net bundle, the enveloping net bundle, which generalizes the notion of universal C*-algebra given by Fredenhagen to nonsimply connected posets. This allows a classification of nets; in particular, we call injective those nets having a faithful embedding into the enveloping net bundle. Injectivity turns out to be equivalent to the existence of faithful representations. We further relate injectivity to a generalized Cech cocycle of the net, and this allows us to give examples of nets exhausting the above classification. Using the results of this paper we shall show, in a forthcoming paper, that any conformal net over S^1 is injective.