We calculate the stress tensor for a quasi-spherical vesicle and we thermally average it in order to obtain the actual, mechanical, surface tension $tau$ of the vesicle. Both closed and poked vesicles are considered. We recover our results for $tau$ by differentiating the free-energy with respect to the proper projected area. We show that $tau$ may become negative well before the transition to oblate shapes and that it may reach quite large negative values in the case of small vesicles. This implies that spherical vesicles may have an inner pressure lower than the outer one.
Within the framework of the Helfrich elastic theory of membranes and of differential geometry we study the possible instabilities of spherical vesicles towards double bubbles. We find that not only temperature, but also magnetic fields can induce topological transformations between spherical vesicles and double bubbles and provide a phase diagram for the equilibrium shapes.
On elastic spherical membranes, there is no stress induced by the bending energy and the corresponding Laplace-Young law does not involve the elastic bending stiffness. However, when considering an axially symmetrical perturbation that pinches the sphere, it induces nontrivial stresses on the entire membrane. In this paper we introduce a theoretical framework to examine the stress induced by perturbations of geometry around the sphere. We find the local balance force equations along the normal direction to the vesicle, and along the unit binormal, tangent to the membrane; likewise, the global balance force equation on closed loops is also examined. We analyze the distribution of stresses on the membrane as the budding transition occurs. For closed membranes we obtain the modified Young-Laplace law that appears as a consequence of this perturbation.
Fluctuations of the interface between coexisting colloidal fluid phases have been measured with confocal microscopy. Due to a very low surface tension, the thermal motions of the interface are so slow, that a record can be made of the positions of the interface. The theory of the interfacial height fluctuations is developed. For a host of correlation functions, the experimental data are compared with the theoretical expressions. The agreement between theory and experiment is remarkably good.
The aim of this work is to study the problem of the existence of a fundamental relation between the interfacial tension of a system of two partially miscible liquids and the surface tensions of the pure substances. It is shown that these properties cannot be correlated from the physical point of view. However, an accurate relation between them may be developed using a mathematical artifact. In the light of this work, the basis of the empirical formula of Girifalco and Good is examined. The weakness of this formula as well as the approximation leading to it are exposed and discussed and, a new equation connecting interfacial and surface tensions is proposed.
We study the intermittent fluorescence of a single molecule, jumping from the light on to the light off state, as a Poisson process modulated by a fluctuating environment. We show that the quasi-periodic and quasi-deterministic environmental fluctuations make the distribution of the times of sojourn in the light off state depart from the exponential form, and that their succession in time mirrors environmental dynamics. As an illustration, we discuss some recent experimental results, where the environmental fluctuations depend on enzymatic activity.