Multiply quantized vortices in the BCS-to-BEC evolution of p-wave resonant Fermi gases are investigated theoretically. The vortex structure and the low-energy quasiparticle states are discussed, based on the self-consistent calculations of the Bogoliubov-de Gennes and gap equations. We reveal the direct relation between the macroscopic structure of vortices, such as particle densities, and the low-lying quasiparticle state. In addition, the net angular momentum for multiply quantized vortices with a vorticity $kappa$ is found to be expressed by a simple equation, which reflects the chirality of the Cooper pairing. Hence, the observation of the particle density depletion and the measurement of the angular momentum will provide the information on the core-bound state and $p$-wave superfluidity. Moreover, the details on the zero energy Majorana state are discussed in the vicinity of the BCS-to-BEC evolution. It is demonstrated numerically that the zero energy Majorana state appears in the weak coupling BCS limit only when the vortex winding number is odd. There exist the $kappa$ branches of the core bound states for a vortex state with vorticity $kappa$, whereas only one of them can be the zero energy. This zero energy state vanishes at the BCS-BEC topological phase transition, because of interference between the core-bound and edge-bound states.
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