Some isolated neutron stars show harmonically spaced absorption features in their thermal soft X-ray spectra. The interpretation of the features as a cyclotron line and its harmonics has been suggested, but the usual explanation of the harmonics as caused by relativistic effects fails because the relativistic corrections are extremely small in this case. We suggest that the features correspond to the peaks in the energy dependence of the free-free opacity in a quantizing magnetic field, known as quantum oscillations. The peaks arise when the transitions to new Landau levels become allowed with increasing the photon energy; they are strongly enhanced by the square-root singularities in the phase-space density of quantum states in the case when the free (non-quantized) motion is effectively one-dimensional. To explore observable properties of these quantum oscillations, we calculate models of hydrogen neutron star atmospheres with B sim 10^{10} - 10^{11} G (i.e., electron cyclotron energy E_{c,e} = 0.1 - 1 keV) and T_{eff} = 1 - 3 MK. Such conditions are thought to be typical for the so-called central compact objects in supernova remnants, such as 1E 1207.4-5209 in PKS 1209-51/52. We show that observable features at the electron cyclotron harmonics form at moderately large values of the quantization parameter, b_{eff} = E_{c,e}/kT_{eff} = 0.5 - 20. The equivalent widths of the features can reach 100 - 200 eV; they grow with increasing b_{eff} and are lower for higher harmonics.
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