An attempt is made to explain the recently reported occurrence of ultradense deuterium as an isothermal transition of Rydberg matter into a high density phase by quantum mechanical exchange forces. It is conjectured that the transition is made possible by the formation of vortices in a Cooper pair electron fluid, separating the electrons from the deuterons, with the deuterons undergoing Bose-Einstein condensation in the core of the vortices. If such a state of deuterium should exist at the reported density of about 100,000 g/cm3, it would greatly facility the ignition of a thermonuclear detonation wave in pure deuterium, by placing the deuterium in a thin disc, to be ignited by a pulsed ultrafast laser or particle beam of modest energy.