No Arabic abstract
We compute models of the transmission spectra of planets HD 209458b, HD 189733b, and generic hot Jupiters. We examine the effects of temperature, surface gravity, and metallicity for the generic planets as a guide to understanding transmission spectra in general. We find that carbon dioxide absorption at 4.4 and 15 microns is prominent at high metallicity, and is a clear metallicity indicator. For HD 209458b and HD 189733b, we compute spectra for both one-dimensional and three-dimensional model atmospheres and examine the differences between them. The differences are usually small, but can be large if atmospheric temperatures are near important chemical abundance boundaries. The calculations for the 3D atmospheres, and their comparison with data, serve as constraints on these dynamical models that complement the secondary eclipse and light curve data sets. For HD 209458b, even if TiO and VO gases are abundant on the day side, their abundances can be considerably reduced on the cooler planetary limb. However, given the predicted limb temperatures and TiO abundances, the models optical opacity is too high. For HD 189733b we find a good match with some infrared data sets and constrain the altitude of a postulated haze layer. For this planet, substantial differences can exist between the transmission spectra of the leading and trailing hemispheres, which is an excellent probe of carbon chemistry. In thermochemical equilibrium, the cooler leading hemisphere is methane-dominated, and the hotter trailing hemisphere is CO-dominated, but these differences may be eliminated by non-equilibrium chemistry due to vertical mixing. It may be possible to constrain the carbon chemistry of this planet, and its spatial variation, with JWST.
We present a grid of forward model transmission spectra, adopting an isothermal temperature-pressure profile, alongside corresponding equilibrium chemical abundances for 117 observationally significant hot exoplanets (Equilibrium Temperatures of 547-2710 K). This model grid has been developed using a 1D radiative-convective-chemical equilibrium model termed ATMO, with up-to-date high temperature opacities. We present an interpretation of observations of ten exoplanets, including best fit parameters and $chi^{2}$ maps. In agreement with previous works, we find a continuum from clear to hazy/cloudy atmospheres for this sample of hot Jupiters. The data for all the 10 planets are consistent with sub-solar to solar C/O ratio, 0.005 to 10 times solar metallicity and water rather than a methane dominated infrared spectra. We then explore the range of simulated atmospheric spectra for different exoplanets, based on characteristics such as temperature, metallicity, C/O-ratio, haziness and cloudiness. We find a transition value for the metallicity between 10 and 50 times solar, which leads to substantial changes in the transmission spectra. We also find a transition value of C/O ratio, from water to carbon species dominated infrared spectra, as found by previous works, revealing a temperature dependence of this transition point ranging from $sim$0.56 to $sim$1-1.3 for equilibrium temperatures from $sim$900 to $sim$2600 K. We highlight the potential of the spectral features of HCN and C$_2$H$_2$ to constrain the metallicities and C/O ratios of planets, using JWST observations. Finally, our entire grid ($sim$460,000 simulations) is publicly available and can be used directly with the JWST simulator PandExo for planning observations.
We present results from a set of simulations using a fully coupled three-dimensional (3D) chemistry-radiation-hydrodynamics model and investigate the effect of transport of chemical species by the large-scale atmospheric flow in hot Jupiter atmospheres. We couple a flexible chemical kinetics scheme to the Met Office Unified Model which enables the study of the interaction of chemistry, radiative transfer and fluid dynamics. We use a newly-released reduced chemical network comprising 30 chemical species that has been specifically developed for application in 3D atmosphere models. We simulate the atmospheres of the well-studied hot Jupiters HD~209458b and HD~189733b which both have dayside--nightside temperature contrasts of several hundred Kelvin and superrotating equatorial jets. We find qualitatively quite different chemical structures between the two planets, particularly for methane (CH$_4$), when advection of chemical species is included. Our results show that consideration of 3D chemical transport is vital in understanding the chemical composition of hot Jupiter atmospheres. 3D mixing leads to significant changes in the abundances of absorbing gas-phase species compared with what would be expected by assuming local chemical equilibrium, or from models including 1D - and even 2D - chemical mixing. We find that CH$_4$, carbon dioxide (CO$_2$) and ammonia (NH$_3$) are particularly interesting as 3D mixing of these species leads to prominent signatures of out-of-equilibrium chemistry in the transmission and emission spectra, detectable with near-future instruments.
Radiative transfer in planetary atmospheres is usually treated in the static limit, i.e., neglecting atmospheric motions. We argue that hot Jupiter atmospheres, with possibly fast (sonic) wind speeds, may require a more strongly coupled treatment, formally in the regime of radiation-hydrodynamics. To lowest order in v/c, relativistic Doppler shifts distort line profiles along optical paths with finite wind velocity gradients. This leads to flow-dependent deviations in the effective emission and absorption properties of the atmospheric medium. Evaluating the overall impact of these distortions on the radiative structure of a dynamic atmosphere is non-trivial. We present transmissivity and systematic equivalent width excess calculations which suggest possibly important consequences for radiation transport in hot Jupiter atmospheres. If winds are fast and bulk Doppler shifts are indeed important for the global radiative balance, accurate modeling and reliable data interpretation for hot Jupiter atmospheres may prove challenging: it would involve anisotropic and dynamic radiative transfer in a coupled radiation-hydrodynamical flow. On the bright side, it would also imply that the emergent properties of hot Jupiter atmospheres are more direct tracers of their atmospheric flows than is the case for Solar System planets. Radiation-hydrodynamics may also influence radiative transfer in other classes of hot exoplanetary atmospheres with fast winds.
In this work we study the effect of disequilibrium processes on mixing ratio profiles of neutral species and on the simulated spectra of a hot Jupiter exoplanet that orbits stars of different spectral types. We also address the impact of stellar activity that should be present to a different degree in all stars with convective envelopes. We used the VULCAN chemical kinetic code to compute number densities of species. The temperature-pressure profile of the atmosphere was computed with the HELIOS code. We also utilized the $tau$-ReX forward model to predict the spectra of planets in primary and secondary eclipses. In order to account for the stellar activity we made use of the observed solar XUV spectrum taken from Virtual Planetary Laboratory (VPL) as a proxy for an active sun-like star. We find large changes in mixing ratios of most chemical species in planets orbiting A-type stars that radiate strong XUV flux inducing a very effective photodissociation. For some species, these changes can propagate very deep into the planetary atmosphere to pressures of around 1 bar. To observe disequilibrium chemistry we favor hot Jupiters with temperatures Teq=1000 K and ultra-hot Jupiters with Teq=3000$ K that also have temperature inversion in their atmospheres. On the other hand, disequilibrium calculations predict little changes in spectra of planets with intermediate temperatures. We also show that stellar activity similar to the one of the modern Sun drives important changes in mixing ratio profiles of atmospheric species. However, these changes take place at very high atmospheric altitudes and thus do not affect predicted spectra. We estimate that the effect of disequilibrium chemistry in planets orbiting nearby bright stars could be robustly detected and studied with future missions with spectroscopic capabilities in infrared such as, e.g., JWST and ARIEL.