Within the Standard model with the 4th generation quarks b and t we have analyzed CP-violating flavor changing neutral current processes t -> cX; b-> sX, b-> bX,t-> cX, and t-> tX, with X=Z,H,gamma,g, by constructing and employing global, unique fit for the 4th generation mass mixing matrix CKM4 at 300 < m_t < 700 GeV. All quantities appearing in the CKM4 were subject to our fitting procedure. We have found that our fit produces the following CP partial rate asymmetry dominance: a_CP(b-> s(Z,H,gamma,g))= (90,73,52,30)%, at m_t ~ 300,300,380,400 GeV, respectively. From the experimental point of view the best decay mode, out of the above four, is certainly b-> s gamma, because of the presence of a clean high energy single final state photon. We have also obtained relatively large a_CP(t -> c g) ~ 15 (10)% for t running in the loops with the mass m_t= 650(500) GeV. There are fair chances that the 4th generation quarks will be discovered at Tevatron or LHC and that some of their decay rates shall be measured. If b and t exist at energies we assumed, with well executed tagging, large a_CP could be found too.
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