In this paper, code pairs based on trellis coded modulation are proposed over PSK signal sets for a two-user Gaussian multiple access channel. In order to provide unique decodability property to the receiver and to maximally enlarge the constellation constrained (CC) capacity region, a relative angle of rotation is introduced between the signal sets. Subsequently, the structure of the textit{sum alphabet} of two PSK signal sets is exploited to prove that Ungerboeck labelling on the trellis of each user maximizes the guaranteed minimum squared Euclidean distance, $d^{2}_{g, min}$ in the textit{sum trellis}. Hence, such a labelling scheme can be used systematically to construct trellis code pairs for a two-user GMAC to approach emph{any rate pair} within the capacity region.
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