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Register a new userThe Chemistry of Population III Supernova Ejecta: I - Formation of Molecules in the Early Universe
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Added by
Isabelle Cherchneff
Publication date
2009
fields
Physics
and research's language is
English
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We study the formation and destruction of molecules in the ejecta of Population III supernovae (SNe) using a chemical kinetic approach to follow the evolution of molecular abundances from day 100 to day 1000 after explosion. The chemical species included range from simple di-atomic molecules to more complex dust precursor species. All relevant chemical processes that are unique to the SN environment are considered. Our work focuses on zero-metallicity progenitors with masses of 20, 170, and 270 Msun, and we study the effect of different levels of heavy element mixing and the inward diffusion of hydrogen on the ejecta chemistry. We show that the ejecta chemistry does not reach a steady state within the relevant time-span for molecule formation. The primary species formed are O2, CO, SiS, and SO. The SiO, formed as early as 200 days after explosion, is rapidly depleted by the formation of silica molecular precursors in the ejecta. The rapid conversion of CO to C2 and its thermal fractionation at temperatures above 5000 K allow for the formation of carbon chains in the oxygen-rich zone of the unmixed models, providing an important pathway for the formation of carbon dust in hot environments where the C/O ratio is less than 1. We show that the fully-mixed ejecta of a 170 Msun progenitor synthesizes 11.3 Mun of molecules whereas 20 Msun and 270 Msun progenitors produce 0.78, and 3.2 Msun of molecules, respectively. The admixing of 10 % of hydrogen into the fully-mixed ejecta of the 170 Msun progenitor increases its molecular yield to ~ 47Msun. The unmixed ejecta of a 170 Msun progenitor supernova without hydrogen penetration synthesizes ~37 Msun of molecules, whereas its 20 Msun counterpart produces ~ 1.2 Msun. Finally, we discuss the cosmological implication of molecule formation by Pop. III SNe in the early universe.
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The first molecules detected at infrared wavelengths in the ejecta of a Type II supernova, namely SN1987A, consisted of CO and SiO. Since then, confirmation of the formation of these two species in several other supernovae a few hundred days after explosion has been obtained. However, supernova environments appear to hamper the synthesis of large, complex species due to the lack of microscopically-mixed hydrogen deep in supernova cores. Because these environments also form carbon and silicate dust, it is of importance to understand the role played by molecules in the depletion of elements and how chemical species get incorporated into dust grains. In the present paper, we review our current knowledge of the molecular component of supernova ejecta, and present new trends and results on the synthesis of molecules in these harsh, explosive events.
Core-collapse supernovae are considered to be important contributors to the primitive dust enrichment of the interstellar medium in the high-redshift universe. Theoretical models of dust formation in stellar explosions have so far provided controversial results and a generally poor fit to the observations of dust formation in local supernovae. We present a new methodology for the calculation of carbonaceous dust formation in young supernova remnants. Our new technique uses both the nucleation theory and a chemical reaction network to allow us to compute the dust growth beyond the molecular level as well as to consider chemical erosion of the forming grains. We find that carbonaceous dust forms efficiently in the core of the ejecta, but takes several years to condensate, longer than previously estimated. It forms unevenly and remains concentrated in the inner part of the remnant. These results support the role of core-collapse supernovae as dust factories and provide new insight on the observations of SN 1987A, in which large amounts of dust have been detected to form on a timescale of years after core collapse.
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