Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userPressure effect on the melting temperature
88
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Pressure-melting temperature relationship is proposed and tested against the experiments of metals (Pt and Al), salt (NaCl), and ceramic (MgO) with positive results. The equation contains one open parameter which remains constant for the investigated substances. The constant value of the parameter indicates that the presented equation for the melting curve might be the first one which does not contain any arbitrary constant which is left open to fit to the experiments.
rate research
Read More
Adding salt to water at ambient pressure affects its thermodynamic properties. At low salt concentration, anomalies such as the density maximum are shifted to lower temperature, while at large enough salt concentration they cannot be observed any more. Here we investigate the effect of salt on an anomaly recently observed in pure water at negative pressure: the existence of a sound velocity minimum along isochores. We compare experiments and simulations for an aqueous solution of sodium chloride with molality around $1.2,mathrm{mol,kg^{-1}}$, reaching pressures beyond $-100,mathrm{MPa}$. We also discuss the origin of the minima in the sound velocity and emphasize the importance of the relative position of the temperatures of sound velocity and density anomalies.
There has been a major controversy over the past seven years about the high-pressure melting curves of transition metals. Static compression (diamond-anvil cell: DAC) experiments up to the Mbar region give very low melting slopes dT_m/dP, but shock-wave (SW) data reveal transitions indicating much larger dT_m/dP values. Ab initio calculations support the correctness of the shock data. In a very recent letter, Belonoshko et al. propose a simple and elegant resolution of this conflict for molybdenum. Using ab initio calculations based on density functional theory (DFT), they show that the high-P/high-T phase diagram of Mo must be more complex than was hitherto thought. Their calculations give convincing evidence that there is a transition boundary between the normal bcc structure of Mo and a high-T phase, which they suggest could be fcc. They propose that this transition was misinterpreted as melting in DAC experiments. In confirmation, they note that their boundary also explains a transition seen in the SW data. We regard Belonoshko et al.s Letter as extremely important, but we note that it raises some puzzling questions, and we believe that their proposed phase diagram cannot be completely correct. We have calculated the Helmholtz and Gibbs free energies of the bcc, fcc and hcp phases of Mo, using essentially the same quasiharmonic methods as used by Belonoshko et al.; we find that at high-P and T Mo in the hcp structure is more stable than in bcc or fcc.
New model describing the pressure effect on the melting temperature is proposed by using four assumptions. One, the average wavelength of the phonon vibration at the Debye temperature corresponds to the length of the unit cell. Two, the phonon vibration at the melting temperature is in self-resonance with the lattice vibration of the surface atomic/molecular layer. Three, the phonon wavelength ratio of the Debye and the melting temperature does not be affected by the pressure. Four the pressure reduces the anharmonic part of the vibration. The relevant equations are derived and tested against the experiments of sodium with positive result.
We study the initial stages of homogeneous melting of a hexagonal ice crystal at coexistence and at moderate superheating. Our trajectory-based computer simulation approach provides a comprehensive picture of the events that lead to melting; from the initial accumulation of 5+7 defects, via the formation of L-D and interstitial-vacancy pairs, to the formation of a liquid nucleus. Of the different types of defects that we observe to be involved in melting, a particular kind of 5+7 type defect (type 5) plays a prominent role as it often forms prior to the formation of the initial liquid nucleus and close to the site where the nucleus forms. Hence, like other solids, ice homogeneously melts via the prior accumulation of defects.
Autoignition delay experiments for the isomers of butanol, including n-, sec-, tert-, and iso-butanol, have been performed using a heated rapid compression machine. For a compressed pressure of 15 bar, the compressed temperatures have been varied in the range of 725-855 K for all the stoichiometric fuel/oxidizer mixtures. Over the conditions investigated in this study, the ignition delay decreases monotonically as temperature increases and exhibits single-stage characteristics. Experimental ignition delays are also compared to simulations computed using three kinetic mechanisms available in the literature. Reasonable agreement is found for three isomers (tert-, iso-, and n-butanol).
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
