No Arabic abstract
We study an instability of thin liquid-vapor layers bounded by rigid parallel walls from both below and above. In this system, the interfacial instability is induced by lateral vapor pressure fluctuation, which is in turn attributed to the effect of phase change: evaporation occurs at a hotter portion of the interface and condensation at a colder one. The high vapor pressure pushes the interface downward and the low one pulls it upward. A set of equations describing the temporal evolution of the interface of the liquid-vapor layers is derived. This model neglects the effect of mass loss or gain at the interface and guarantees the mass conservation of the liquid layer. The result of linear stability analysis of the model shows that the presence of the pressure dependence of the local saturation temperature mitigates the growth of long-wave disturbances. The thinner vapor layer enhances the vapor pressure effect. We find the stability criterion, which suggests that only slight temperature gradients are sufficient to overcome the gravitational effect for a water/vapor system. The same holds for the Rayleigh-Taylor unstable case, with a possibility that the vapor pressure effect may be weakened if the accommodation coefficient is below a certain critical value.
Remaining within the pure hydrodynamic approach, we formulate a self-consistent model for simulating the dynamic behavior of matter passing through metastable states in the two-phase liquid-vapor region of the phase diagram. The model is based on the local criterion of explosive boiling, derived by applying the theory of homogeneous bubble nucleation in superheated liquids. Practical application of the proposed model is illustrated with hydrodynamic simulations of a volumetrically uniformly heated planar layer of fused silica SiO2. Implications for experimentally measurable quantities are briefly discussed. A newly developed equation of state, based on the well known QEOS model and capable of handling homogeneous mixtures of elements, was used in the numerical simulations.
The understanding of the shrinkage dynamics of plasmonic bubbles formed around metallic nanoparticles immersed in liquid and irradiated by a resonant light source is crucial for the usage of these bubbles in numerous applications. In this paper we experimentally show and theoretically explain that a plasmonic bubble during its shrinkage undergoes two different phases: first, a rapid partial bubble shrinkage governed by vapor condensation and, second, a slow diffusion-controlled bubble dissolution. The history of the bubble formation plays an important role in the shrinkage dynamics during the first phase, as it determines the gas-vapor ratio in the bubble composition. Higher laser powers lead to more vaporous bubbles, while longer pulses and higher dissolved air concentrations lead to more gaseous bubbles. The dynamics of the second phase barely depends on the history of bubble formation, i.e. laser power and pulse duration, but strongly on the dissolved air concentration, which defines the concentration gradient at the bubble interface. Finally, for the bubble dissolution in the second phase, with decreasing dissolved air concentration, we observe a gradual transition from a $R(t) propto (t_0 - t) ^{1/3}$ scaling law to a $R(t) propto (t_0 - t) ^{1/2}$ scaling law, where $t_0$ is the lifetime of the bubble and theoretically explain this transition.
We consider the collapse behavior of cavitation bubbles near walls under high ambient pressure conditions. Generic configurations with different stand-off distances are investigated by numerical simulation using a fully compressible two-phase flow solver including phase change. The results show that the stand-off distance has significant effects on collapse dynamics, micro-jet formation, rebound, and maximum wall pressure. A relation between cavitation induced material damage and corresponding collapse mechanisms is obtained from pressure-impact data at the wall. We analyze the resolution dependence of collapse and rebound and the observed maximum pressure distributions. The comparison of the results on six different grid resolutions shows that main collapse features are already captured on the coarsest resolution, while the peak pressures are strongly resolution dependent.
Combining MoS$_2$ monolayers to form multilayers allows to access new functionalities. In this work, we examine the correlation between the stacking order and the interlayer coupling of valence states in MoS$_2$ homobilayer samples grown by chemical vapor deposition (CVD) and artificially stacked bilayers from CVD monolayers. We show that hole delocalization over the bilayer is allowed in 2H stacking and results in strong interlayer exciton absorption and also in a larger A-B exciton separation as compared to 3R bilayers, where both holes and electrons are confined to the individual layers. Comparing 2H and 3R reflectivity spectra allows to extract an interlayer coupling energy of about $t_perp=49$ meV. Obtaining very similar results for as-grown and artificially stacked bilayers is promising for assembling large area van der Waals structures with CVD material, using interlayer exciton absorption and A-B exciton separation as indicators for interlayer coupling. Beyond DFT calculations including excitonic effects confirm signatures of efficient interlayer coupling for 2H stacking in agreement with our experiments.
Drop condensation and evaportation as a result of the gradient in vapor concentration are important in both engineering and natural systems. One of the interesting natural examples is transpiration on plant leaves. Most of water in the inner space of the leaves escapes through stomata, whose rate depends on the surface topography and a difference in vapor concentrations inside and just outside of the leaves. Previous research on the vapor flux on various surfaces has focused on numerically solving the vapor diffusion equation or using scaling arguments based on a simple solution with a flat surface. In this present work, we present and discuss simple analytical solutions on various 2D surface shapes (e.g., semicylinder, semi-ellipse, hair). The method of solving the diffusion equation is to use the complex potential theory, which provides analytical solutions for vapor concentration and flux. We find that a high mass flux of vapor is formed near the top of the microstructures while a low mass flux is developed near the stomata at the leaf surface. Such a low vapor flux near the stomata may affect transpiration in two ways. First, condensed droplets on the stomata will not grow due to a low mass flux of vapor, which will not inhibit the gas exchange through the stomatal opening. Second, the low mass flux from the atmosphere will facilitate the release of high concentrated vapor from the substomatal space.