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Register a new userThe 5.25 & 5.7 $mu$m Astronomical Polycyclic Aromatic Hydrocarbon Emission Features
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Astronomical mid-IR spectra show two minor PAH features at 5.25 and 5.7 $mu$m (1905 and 1754 cm$^{rm - 1}$) that hitherto have been little studied, but contain information about the astronomical PAH population that complements that of the major emission bands. Here we report a study involving both laboratory and theoretical analysis of the fundamentals of PAH spectroscopy that produce features in this region and use these to analyze the astronomical spectra. The ISO SWS spectra of fifteen objects showing these PAH features were considered for this study, of which four have sufficient S/N between 5 and 6 $mu$m to allow for an in-depth analysis. All four astronomical spectra show similar peak positions and profiles. The 5.25 $mu$m feature is peaked and asymmetric, while the 5.7 $mu$m feature is broader and flatter. Detailed analysis of the laboratory spectra and quantum chemical calculations show that the astronomical 5.25 and 5.7 $mu$m bands are a blend of combination, difference and overtone bands primarily involving CH stretching and CH in-plane and CH out-of-plane bending fundamental vibrations. The experimental and computational spectra show that, of all the hydrogen adjacency classes possible on PAHs, solo and duo hydrogens consistently produce prominent bands at the observed positions whereas quartet hydrogens do not. In all, this a study supports the picture that astronomical PAHs are large with compact, regular structures. From the coupling with primarily strong CH out-of-plane bending modes one might surmise that the 5.25 and 5.7 $mu$m bands track the neutral PAH population. However, theory suggests the role of charge in these astronomical bands might also be important.
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We examine polycyclic aromatic hydrocarbon (PAH), dust and atomic/molecular emission toward the Galactic bulge using Spitzer Space Telescope observations of four fields: C32, C35, OGLE and NGC 6522. These fields are approximately centered on (l, b) = (0.0{deg}, 1.0{deg}), (0.0{deg}, -1.0{deg}), (0.4{deg}, -2.1{deg}) and (1.0{deg}, -3.8{deg}), respectively. Far-infrared photometric observations complement the Spitzer/IRS spectroscopic data and are used to construct spectral energy distributions. We find that the dust and PAH emission are exceptionally similar between C32 and C35 overall, in part explained due to their locations---they reside on or near boundaries of a 7 Myr-old Galactic outflow event and are partly shock-heated. Within the C32 and C35 fields, we identify a region of elevated H{alpha} emission that is coincident with elevated fine-structure and [O IV] line emission and weak PAH feature strengths. We are likely tracing a transition zone of the outflow into the nascent environment. PAH abundances in these fields are slightly depressed relative to typical ISM values. In the OGLE and NGC 6522 fields, we observe weak features on a continuum dominated by zodiacal dust. SED fitting indicates that thermal dust grains in C32 and C35 have comparable temperatures to those of diffuse, high-latitude cirrus clouds. Little variability is detected in the PAH properties between C32 and C35, indicating that a stable population of PAHs dominates the overall spectral appearance. In fact, their PAH features are exceptionally similar to that of the M82 superwind, emphasizing that we are probing a local Galactic wind environment.
We report new properties of the 11 and 12.7 {mu}m emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution textit{Spitzer} Space Telescope data, we study in detail the spectral and spatial characteristics of the 11 and 12.7 {mu}m emission bands in maps of reflection nebulae NGC 7023 and NGC 2023 (North and South) and the star-forming region M17. Profile variations are observed in both the 11 and 12.7 {mu}m emission bands. We identify a neutral contribution to the traditional 11.0 {mu}m PAH band and a cationic contribution to the traditional 11.2 {mu}m band, the latter of which affects the PAH class of the 11.2 {mu}m emission in our sample. The peak variations of the 12.7 {mu}m complex are explained by the competition between two underlying blended components. The spatial distributions of these components link them to cations and neutrals. We conclude that the 12.7 {mu}m emission originates in both neutral and cationic PAHs, lending support to the use of the 12.7/11.2 intensity ratio as a charge proxy.
We present evidence for the existence of an IRAC excess in the spectral energy distribution (SED) of 5 galaxies at 0.6<z<0.9 and 1 galaxy at z=1.7. These 6 galaxies, located in the Great Observatories Origins Deep Survey field (GOODS-N), are star forming since they present strong 6.2, 7.7, and 11.3 um polycyclic aromatic hydrocarbon (PAH) lines in their Spitzer IRS mid-infrared spectra. We use a library of templates computed with PEGASE.2 to fit their multiwavelength photometry and derive their stellar continuum. Subtraction of the stellar continuum enables us to detect in 5 galaxies a significant excess in the IRAC band pass where the 3.3 um PAH is expected. We then assess if the physical origin of the IRAC excess is due to an obscured active galactic nucleus (AGN) or warm dust emission. For one galaxy evidence of an obscured AGN is found, while the remaining four do not exhibit any significant AGN activity. Possible contamination by warm dust continuum of unknown origin as found in the Galactic diffuse emission is discussed. The properties of such a continuum would have to be different from the local Universe to explain the measured IRAC excess, but we cannot definitively rule out this possibility until its origin is understood. Assuming that the IRAC excess is dominated by the 3.3 um PAH feature, we find good agreement with the observed 11.3 um PAH line flux arising from the same C-H bending and stretching modes, consistent with model expectations. Finally, the IRAC excess appears to be correlated with the star-formation rate in the galaxies. Hence it could provide a powerful diagnostic for measuring dusty star formation in z>3 galaxies once the mid-infrared spectroscopic capabilities of the James Webb Space Telescope become available.
Context: PAHs appear to be an ubiquitous interstellar dust component but the effects of shocks waves upon them have never been fully investigated. Aims: To study the effects of energetic (~0.01-1 keV) ion (H, He and C) and electron collisions on PAHs in interstellar shock waves.Methods: We calculate the ion-PAH and electron-PAH nuclear and electronic interactions, above the threshold for carbon atom loss from a PAH, in 50-200 km/s shock waves in the warm intercloud medium. Results: Interstellar PAHs (Nc = 50) do not survive in shocks with velocities greater than 100 km/s and larger PAHs (Nc = 200) are destroyed for shocks with velocities greater/equal to 125 km/s. For shocks in the ~75 - 100 km/s range, where destruction is not complete, the PAH structure is likely to be severely denatured by the loss of an important fraction (20-40%) of the carbon atoms. We derive typical PAH lifetimes of the order of a few x10^8 yr for the Galaxy. These results are robust and independent of the uncertainties in some key parameters that have yet to be well-determined experimentally. Conclusions: The observation of PAH emission in shock regions implies that that emission either arises outside the shocked region or that those regions entrain denser clumps that, unless they are completely ablated and eroded in the shocked gas, allow dust and PAHs to survive in extreme environments.
Context: Cosmic rays are present in almost all phases of the ISM. PAHs and cosmic rays represent an abundant and ubiquitous component of the interstellar medium. However, the interaction between them has never before been fully investigated. Aims: To study the effects of cosmic ray ion (H, He, CNO and Fe-Co-Ni) and electron bombardment of PAHs in galactic and extragalactic environments. Methods: We calculate the nuclear and electronic interactions for collisions between PAHs and cosmic ray ions and electrons with energies between 5 MeV/nucleon and 10 GeV, above the threshold for carbon atom loss, in normal galaxies, starburst galaxies and cooling flow galaxy clusters. Results: The timescale for PAH destruction by cosmic ray ions depends on the electronic excitation energy Eo and on the amount of energy available for dissociation. Small PAHs are destroyed faster, with He and the CNO group being the more effective projectiles. For electron collisions, the lifetime is independent of the PAH size and varies with the threshold energy To. Conclusions: Cosmic rays process the PAHs in diffuse clouds, where the destruction due to interstellar shocks is less efficient. In the hot gas filling galactic halos, outflows of starburst galaxies and intra-cluster medium, PAH destruction is dominated by collisions with thermal ions and electrons, but this mechanism is ineffective if the molecules are in denser cloudlets and isolated from the hot gas. Cosmic rays can access the denser clouds and together with X-rays will set the lifetime of those protected PAHs. This limits the use of PAHs as a`dye for tracing the presence of cold entrained material.
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