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Register a new userObservation of a novel orbital selective Mott transition in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$
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Electrons in a simple correlated system behave either as itinerant charge carriers or as localized moments. However, there is growing evidence for the coexistence of itinerant electrons and local moments in transition metals with nearly degenerate $d$-orbitals. It demands one or more selective electron orbitals undergo the Mott transition while the others remain itinerant. Here we report the first observation of such an orbital selective Mott transition (OSMT) in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ by angle-resolved photoemission spectroscopy (ARPES). While we observed two sets of dispersing bands and Fermi surface associated with the doubly-degenerate $d_{yz}$ and $d_{zx}$ orbitals, the Fermi surface associated with the wider $d_{xy}$ band is missing, a consequence of selective Mott localization. Our theoretical calculations demonstrate that this novel OSMT is mainly driven by the combined effects of interorbital carrier transfer, superlattice potential, and orbital degeneracy, whereas the bandwidth difference plays a less important role.
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We present a comprehensive angle-resolved photoemission spectroscopy study of Ca$_{1.8}$Sr$_{0.2}$RuO$_4$. Four distinct bands are revealed and along the Ru-O bond direction their orbital characters are identified through a light polarization analysis and comparison to dynamical mean-field theory calculations. Bands assigned to $d_{xz}, d_{yz}$ orbitals display Fermi liquid behavior with fourfold quasiparticle mass renormalization. Extremely heavy fermions - associated with a predominantly $d_{xy}$ band character - are shown to display non-Fermi-liquid behavior. We thus demonstrate that Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ is a hybrid metal with an orbitally selective Fermi liquid quasiparticle breakdown.
The magnetoelastic coupling in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ and in Ca$_{1.5}$Sr$_{0.5}$RuO$_4$ has been studied combining high-resolution dilatometer and diffraction techniques. Both compounds exhibit strong anomalies in the thermal-expansion coefficient at zero and at high magnetic field as well as an exceptionally large magnetostriction. All these structural effects, which are strongest in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$, point to a redistribution of electrons between the different $t_{2g}$ orbitals tuned by temperature and magnetic field. The temperature and the field dependence of the thermal-expansion anomalies in Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ yield evidence for a critical end-point lying close to the low-temperature metamagnetic transition; however, the expected scaling relations are not well fulfilled.
We report an electrical transport study in Ca$_{2-x}$Sr$_{x}$RuO$_4$ single crystals at high magnetic fields ($B$). For $x =0.2$, the Hall constant $R_{xy}$ decreases sharply at an anisotropic metamagnetic (MM) transition reaching its value for Sr$_2$RuO$_4$ at high fields. A sharp decrease in the $A$ coefficient of the resistivity $T^2$-term and a change in the structure of the angular magnetoresistance oscillations (AMRO) for $B$ rotating in the planes, confirms the reconstruction of the Fermi surface (FS). Our observations and LDA calculations indicate a strong dependence of the FS on the Ca concentration and suggest the coexistence of itinerant and localized electronic states in single layered ruthenates.
The alloy Ca$_{2-x}$Sr$_x$RuO$_4$ exhibits a complex phase diagram with peculiar magnetic metallic phases. In this paper some aspects of this alloy are discussed based on a mean field theory for an effective Kugel-Khomskii model of localized orbital and spin degrees of freedom. This model results from an orbital selective Mott transition which in the three-band system localized two orbitals while leaving the third one itinerant. Special attention is given to the region around a structure quantum phase transition at $ x approx 0.5 $ where the crystal lattice changes from tetragonal to orthorhombic symmetry while leaving the system metallic. This transition yields, a change from ferromagnetic to antiferromagnetic spin correlations. The complete mean field phase diagram for this transition is given including orbital and spin order. The anisotropy of spin susceptibility, a consequence of spin-orbit coupling and orbital correlation, is a tell-tale sign of one of these phases. In the predominantly antiferromagnetic phase we describe a metamagnetic transition in a magnetic field and show that coupling of the itinerant band to the localized degrees of freedom yields an anomalous longitudinal magnetoresistance transition. Both phenomena are connected with the evolution of the ferromagnetic and antiferromagnetic domains in the external magnetic field and agree qualitatively with the experimental findings.
We have studied the influence of a magnetic field on the thermodynamic properties of Ca$_{2-x}$Sr$_{x}$RuO$_4$ in the intermediate metallic region with tilt and rotational distortions ($0.2leq x leq 0.5$). We find strong and anisotropic thermal expansion anomalies at low temperatures, which are suppressed and even reversed by a magnetic field. The metamagnetic transition of Ca$_{1.8}$Sr$_{0.2}$RuO$_4$ is accompanied by a large magnetostriction. Furthermore, we observe a strong magnetic-field dependence of $c_p/T$, that can be explained by magnetic fluctuations.
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