The systematic data set on isotopic effects in spectator fragmentation collected recently at the GSI laboratory permits the investigation of the N/Z dependence of the nuclear caloric curve which is of interest in several respects. In particular, new light is shed on the proposed interpretation of chemical breakup temperatures as a manifestation of the limiting temperatures predicted by the Hartree-Fock model. The obtained results are discussed within the general context of temperature measurements in multifragmentation reactions.
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