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Register a new userElectrostatic extraction of cold molecules from a cryogenic reservoir
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We present a method which delivers a continuous, high-density beam of slow and internally cold polar molecules. In our source, warm molecules are first cooled by collisions with a cryogenic helium buffer gas. Cold molecules are then extracted by means of an electrostatic quadrupole guide. For ND$_3$ the source produces fluxes up to $(7 pm ^{7}_{4}) times 10^{10}$ molecules/s with peak densities up to $(1.0 pm ^{1.0}_{0.6}) times 10^9$ molecules/cm$^3$. For H$_2$CO the population of rovibrational states is monitored by depletion spectroscopy, resulting in single-state populations up to $(82 pm 10)%$.
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Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both species are in a beam, where one species is trapped, or when both species are trapped. Simultaneous trapping offers significantly longer interaction times and an associated increased sensitivity to rare collision events. However, there are significant practical challenges associated with combining atom and molecule systems, which often have competing experimental requirements. Here, we describe in detail an experimental system that allows for studies of cold collisions between ultracold atoms and cold molecules in a dual trap, where the atoms and molecules are trapped using static magnetic and electric fields, respectively. As a demonstration of the systems capabilities, we study cold collisions between ammonia ($^{14}$ND$_{3}$ and $^{15}$ND$_{3}$) molecules and rubidium ($^{87}$Rb and $^{85}$Rb) atoms.
We apply near-threshold laser photodetachment to characterize the rotational quantum level distribution of OH$^-$ ions stored in the cryogenic ion-beam storage ring, DESIREE, at Stockholm University. We find that the stored ions relax to a rotational temperature of 13.4$pm$0.2 K with 94.9$pm$0.3 % of the ions in the rotational ground state. This is consistent with the storage ring temperature of 13.5$pm$0.5 K as measured with eight silicon diodes, but in contrast to all earlier studies in cryogenic traps and rings where the rotational temperatures were always much higher than those of the storage devices at their lowest temperatures. Furthermore, we actively modify the rotational distribution through selective photodetachment to produce an OH$^-$ beam where 99.1$pm$0.1 % of approximately one million stored ions are in the $J$=0 rotational ground state.
Cavity-enhanced frequency comb spectroscopy for molecule detection in the mid-infrared powerfully combines high resolution, high sensitivity, and broad spectral coverage. However, this technique, and essentially all spectroscopic methods, is limited in application to relatively small, simple molecules. Here we integrate comb spectroscopy with continuous, cold samples of molecules produced via buffer gas cooling, thus enabling the study of significantly more complex molecules. We report simultaneous gains in resolution, sensitivity, and bandwidth and demonstrate this combined capability with the first rotationally resolved direct absorption spectra in the CH stretch region of several complex molecules. These include nitromethane (CH$_3$NO$_2$), a model system that presents challenging questions to the understanding of large amplitude vibrational motion, as well as several large organic molecules with fundamental spectroscopic and astrochemical relevance, including naphthalene (C$_{10}$H$_8$), adamantane (C$_{10}$H$_{16}$), and hexamethylenetetramine (C$_{6}$N$_4$H$_{12}$). This general spectroscopic tool has the potential to significantly impact the field of molecular spectroscopy, simultaneously improving efficiency, spectral resolution, and specificity by orders of magnitude. This realization could open up new molecular species and new kinetics for precise investigations, including the study of complex molecules, weakly bound clusters, and cold chemistry.
We present a comprehensive characterization of cold molecular beams from a cryogenic buffer-gas cell, providing an insight into the physics of buffer-gas cooling. Cold molecular beams are extracted from a cryogenic cell by electrostatic guiding, which is also used to measure their velocity distribution. Molecules rotational-state distribution is probed via radio-frequency resonant depletion spectroscopy. With the help of complete trajectory simulations, yielding the guiding efficiency for all of the thermally populated states, we are able to determine both the rotational and the translational temperature of the molecules at the output of the buffer-gas cell. This thermometry method is demonstrated for various regimes of buffer-gas cooling and beam formation as well as for molecular species of different sizes, $rm{CH_3F}$ and $rm{CF_3CCH}$. Comparison between the rotational and translational temperatures provides evidence of faster rotational thermalization for the $rm{CH_3F-He}$ system in the limit of low He density. In addition, the relaxation rates for different rotational states appear to be different.
We present experiments in which an ultra-cold sample of ammonia molecules is released from an electrostatic trap and recaptured after a variable time. It is shown that, by performing adiabatic cooling before releasing the molecules and adiabatic re-compression after they are recaptured, we are able to observe molecules even after more than 10 ms of free expansion. A coherent measurement performed during this time will have a statistical uncertainty that decreases approximately as the inverse of the square root of the expansion time. This offers interesting prospects for high-resolution spectroscopy and precision tests of fundamental physics theories.
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